3-Methyl-6-methyleneoctane

Base Information

• Chemical Name: 3-Methyl-6-methyleneoctane
• CAS No.: 74630-07-2
• Molecular Formula: C10H20
• Molecular Weight: 140.269
• Mol file: 74630-07-2.mol

Synonyms:3-Methyl-6-methyleneoctane

Chemical Property of 3-Methyl-6-methyleneoctane

Chemical Property:

• Boiling Point: 161.0±7.0 °C(Predicted)
• PSA: 0.00000
• Density: 0.742±0.06 g/cm3(Predicted)
• LogP: 3.77890

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Methyl-6-methyleneoctane

There total 5 articles about 3-Methyl-6-methyleneoctane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

3,6-diethyl-3,6-dimethyl-1,2-diazacyclohexene → 2-ethyl-5-methyl-1-heptene (74630-07-2) + 3,6-dimethyl-2-octene + 3,6-diethyl-2,3,6-trimethyl-1-dehydropiperidine

Guidance literature:

With biphenyl; 9,10-Dicyanoanthracene; In acetonitrile; at 20 ℃; Mechanism; Irradiation;

DOI:10.1021/ja00126a039

Reference yield: 44.0%

C10H20N2 → 3,6-dimethyl-oct-3-ene + 2-Methyl-1-butene (563-46-2) + (E)-3,6-Dimethyl-oct-2-ene + 2-ethyl-5-methyl-1-heptene (74630-07-2)

Guidance literature:

In trichlorofluoromethane; at 0 ℃; Further byproducts given. Yields of byproduct given; 1.) -78 deg C, direct photolyses, CFCl₃; 2.) -78 deg C, sensitized photolyses;

DOI:10.1021/ja00388a031

Reference yield:

1-hydroxy-2,5-diethyl-2,5-dimethylpyrrolidine (83350-61-2) → 2-ethyl-5-methyl-1-heptene (74630-07-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) H₂, 2.) HCl, 3.) NaNO₂, 4.) LiAlH₄, 5.) tert-butyl hypochlorite, Et₃N

2: CCl₃F / 0 °C / 1.) -78 deg C, direct photolyses, CFCl₃; 2.) -78 deg C, sensitized photolyses

With hydrogenchloride; lithium aluminium tetrahydride; tert-butylhypochlorite; hydrogen; triethylamine; sodium nitrite; In trichlorofluoromethane;

DOI:10.1021/ja00388a031

upstream raw materials:

1-hydroxy-2,5-diethyl-2,5-dimethylpyrrolidine

2,5-dimethyl-2-ethyl-Δ⁵-pyrroline oxide

5-ethyl-5-nitrohexan-2-one