(6R,4E)-2,6-Dimethyl-1,4,7-octatriene

Base Information

• Chemical Name: (6R,4E)-2,6-Dimethyl-1,4,7-octatriene
• CAS No.: 33303-13-8
• Molecular Formula: C₁₀H₁₆
• Molecular Weight: 136.237
• Mol file: 33303-13-8.mol

Synonyms:(6R,4E)-2,6-Dimethyl-1,4,7-octatriene;trans-Achillene

Chemical Property of (6R,4E)-2,6-Dimethyl-1,4,7-octatriene

Chemical Property:

• PSA: 0.00000
• LogP: 3.33090

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (6R,4E)-2,6-Dimethyl-1,4,7-octatriene

There total 3 articles about (6R,4E)-2,6-Dimethyl-1,4,7-octatriene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ Occimen (33303-12-7,33303-13-8)

Guidance literature:

Achillenol (II), SOCl2/Py.;

DOI:10.1007/BF00595093

Reference yield:

(R)-2,6-dimethyl-octa-4t,7-dien-2-ol (33303-10-5) → (R)-3,7-dimethyl-octa-1,4t,6-triene (33303-08-1) + trans-Achillen (33303-13-8)

Guidance literature:

With boric acid; at 130 ℃; under 150 Torr;

DOI:10.1002/hlca.19710540418

Reference yield:

(-)-(RS)-2,2-dimethyl-3-((R)-3-methyl-penta-1,4-dien-t-yl)-oxirane (33303-09-2,33403-68-8) → trans-Achillen (33303-13-8)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄ / diethyl ether

2: H₃BO₃ / 130 °C / 150 Torr

With lithium aluminium tetrahydride; boric acid; In diethyl ether;

DOI:10.1002/hlca.19710540418

upstream raw materials:

(R)-2,6-dimethyl-octa-4t,7-dien-2-ol

(-)-(RS)-2,2-dimethyl-3-((R)-3-methyl-penta-1,4-dien-t-yl)-oxirane