epi-Inositol hexaacetate

Base Information

• Chemical Name: epi-Inositol hexaacetate
• CAS No.: 20108-71-8
• Molecular Formula: C18H24O12
• Molecular Weight: 432.381
• Mol file: 20108-71-8.mol

Synonyms:epi-Inositol hexaacetate

Chemical Property of epi-Inositol hexaacetate

Chemical Property:

• PSA: 157.80000
• LogP: -0.40980

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of epi-Inositol hexaacetate

There total 21 articles about epi-Inositol hexaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,4-bis-O-tert-butyldiphenylsilyl-L-epi-inositol + acetic anhydride (108-24-7) → hexa-O-acetyl-epi-inositol (20108-71-8)

Guidance literature:

1,4-bis-O-tert-butyldiphenylsilyl-L-epi-inositol; With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 5h; Inert atmosphere; Cooling with ice;

acetic anhydride; With pyridine; dmap; at 50 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c7cc01191a

Reference yield:

acetic anhydride (108-24-7) + deseryladenomycin (76235-11-5) → pentaacetyl L-gulosamine (3006-60-8,4539-83-7,6730-10-5,7772-79-4,7784-54-5,10385-50-9,14086-90-9,26151-16-6,76375-60-5,76375-61-6,95341-98-3,95341-99-4,134451-91-5,134451-96-0,136982-81-5,145375-11-7,148347-15-3) + hexaacetyl (-)-chiro-inositol (1254-38-2,18779-57-2,20097-40-9,20108-52-5,20108-67-2,20108-71-8,29267-03-6,29267-04-7,29307-62-8,70878-34-1,100679-00-3) + nonaacetyl adenobiosamine (76250-03-8)

Guidance literature:

With hydrogen cation; Multistep reaction; 2.) pyridine;

DOI:10.1016/S0040-4039(00)77445-4

Reference yield:

C6H12O6 + acetic anhydride (108-24-7) → inositol peracetate (1254-38-2) + hexa-O-acetyl-epi-inositol (20108-71-8)

Guidance literature:

With pyridine; dmap; for 24h; Inert atmosphere; Reflux;

DOI:10.1016/j.tetlet.2011.05.051

upstream raw materials:

epi-Inositol

acetic anhydride

trans-cyclohexa-3,5-diene-1,2-diyl diacetate

(+/-)-tetraacetylconduritol C

Downstream raw materials:

epi-Inositol