11-Mercaptoundecylhydroquinone

Base Information

Chemical Name:11-Mercaptoundecylhydroquinone
CAS No.:185839-47-8
Molecular Formula:C17H28O2S
Molecular Weight:296.474
Hs Code.:
European Community (EC) Number:663-269-9
DSSTox Substance ID:DTXSID50746401
Nikkaji Number:J776.161I
Wikidata:Q82694912
Mol file:185839-47-8.mol

Synonyms:11-Mercaptoundecylhydroquinone;185839-47-8;2-(11-SULFANYLUNDECYL)BENZENE-1,4-DIOL;MUH;SCHEMBL3191013;DTXSID50746401;2-(11-mercaptoundecyl)hydroquinone;11-Mercaptoundecylhydroquinone, 95%;2-(11-mercaptoundecyl) hydroquinone

Suppliers and Price of 11-Mercaptoundecylhydroquinone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
11-Mercaptoundecylhydroquinone 95%
500mg
$ 410.00

American Custom Chemicals Corporation
11-MERCAPTOUNDECYLHYDROQUINONE 95.00%
500MG
$ 848.93

AK Scientific
11-Mercaptoundecylhydroquinone
500mg
$ 550.00

Total 1 raw suppliers

Chemical Property of 11-Mercaptoundecylhydroquinone

Chemical Property:

Melting Point:86-92℃
PSA：79.26000
LogP:5.08100
Storage Temp.:?20°C
XLogP3:6.3
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:11
Exact Mass:296.18100131
Heavy Atom Count:20
Complexity:223

Purity/Quality:

95 % ^*data from raw suppliers

11-Mercaptoundecylhydroquinone 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 43
Safety Statements: 36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=C(C=C1O)CCCCCCCCCCCS)O
Uses 11-Mercaptoundecylhydroquinone forms a thiol based self-assembled monolayer (SAM) that facilitates the surface modification by immobilizing the surface atoms. It can be used in functionalization of quantum dots for potential application in sensors and other optoelectronics devices. It can also be coated on the gold electrode for electrical energy storage.

Technology Process of 11-Mercaptoundecylhydroquinone

There total 8 articles about 11-Mercaptoundecylhydroquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 401846-18-2
11-(2,5-dihydroxyphenyl)-1-(thioacetyl)undecane

: 185839-47-8
11-(2,5-dihydroxyphenyl)-1-mercaptoundecane

Guidance literature:: With hydrogenchloride; In methanol; for 10h; Heating;
DOI:10.1021/ja010740n

Reference yield:

: 150-78-7
1,4-dimethoxybezene

: 185839-47-8
11-(2,5-dihydroxyphenyl)-1-mercaptoundecane

Guidance literature:: Multi-step reaction with 4 steps

1.1: n-BuLi; tetramethylethylenediamine / tetrahydrofuran; hexane / 1.5 h / 0 °C

1.2: 79 percent / tetrahydrofuran; hexane / 10 h / 20 °C

2.1: 98 percent / AIBN / tetrahydrofuran / 5 h / UV-irradiation

3.1: 93 percent / BBr₃ / CH₂Cl₂ / 2 h / 20 °C

4.1: 99 percent / concd. HCl / methanol / 10 h / Heating

With hydrogenchloride; n-butyllithium; 2,2'-azobis(isobutyronitrile); N,N,N,N,-tetramethylethylenediamine; boron tribromide; In tetrahydrofuran; methanol; hexane; dichloromethane;
DOI:10.1021/ja010740n

Reference yield:

: 7766-50-9
1-undecen-11-ylbromide

: 185839-47-8
11-(2,5-dihydroxyphenyl)-1-mercaptoundecane

Guidance literature:: Multi-step reaction with 4 steps

1.1: n-BuLi; tetramethylethylenediamine / tetrahydrofuran; hexane / 1.5 h / 0 °C

1.2: 79 percent / tetrahydrofuran; hexane / 10 h / 20 °C

2.1: 98 percent / AIBN / tetrahydrofuran / 5 h / UV-irradiation

3.1: 93 percent / BBr₃ / CH₂Cl₂ / 2 h / 20 °C

4.1: 99 percent / concd. HCl / methanol / 10 h / Heating

With hydrogenchloride; n-butyllithium; 2,2'-azobis(isobutyronitrile); N,N,N,N,-tetramethylethylenediamine; boron tribromide; In tetrahydrofuran; methanol; hexane; dichloromethane;
DOI:10.1021/ja010740n