Tris(2,2'-bipyridine)ruthenium bis(hexafluorophosphate)

Base Information

• Chemical Name: Tris(2,2'-bipyridine)ruthenium bis(hexafluorophosphate)
• CAS No.: 60804-74-2
• Molecular Formula: C30H24F12N6P2Ru
• Molecular Weight: 714.6
• Hs Code.: 28439000
• European Community (EC) Number: 694-406-0
• Mol file: 60804-74-2.mol

Synonyms:60804-74-2;Tris(2,2'-bipyridine)ruthenium bis(hexafluorophosphate);TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) HEXAFLUOROPHOSPHATE;2-pyridin-2-ylpyridine;ruthenium(2+);dihexafluorophosphate;Tris(2,2'-bipyridine)ruthenium(II) Bis(hexafluorophosphate);C30H24F12N6P2Ru;SY100707;T3435;C75843;EN300-7542598;A913607;Ruthenium-tris(2,2'-bipyridyl) dihexafluorophosphate;Tris(2,2'-bipyridine)rutheniumbis(hexafluorophosphate);Tris(2,2''-bipyridine)ruthenium(II) hexafluorophosphate;Tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate, 97%;?(2)-RUTHENIUM(2+) TRIS(BIPYRIDYL) DIHEXAFLUOROPHOSPHATE;Tris(2,2 inverted exclamation mark -bipyridine)ruthenium Bis(hexafluorophosphate);lambda2-ruthenium(2+) ion tris(2-(pyridin-2-yl)pyridine) bis(hexafluoro-lambda5-phosphanuide)

Chemical Property of Tris(2,2'-bipyridine)ruthenium bis(hexafluorophosphate)

Chemical Property:

• Melting Point: >300°C
• PSA: 50.46000
• LogP: 8.42500
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 20
• Rotatable Bond Count: 3
• Exact Mass: 860.038947
• Heavy Atom Count: 51
• Complexity: 183

Purity/Quality:

97% ^*data from raw suppliers

Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ru+2]
• General Description: TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) HEXAFLUOROPHOSPHATE (Ru(bpy)3(PF6)2) is a highly effective photoredox catalyst used in visible light-mediated reactions, such as the dehydrogenative β-arylsulfonylation of tertiary aliphatic amines with arylsulfonyl chlorides. It enables efficient and rapid synthesis of β-arylsulfonyl enamines under mild conditions (e.g., in non-pretreated acetone open to air) without requiring additives, showcasing its utility in green and sustainable chemistry. The catalyst facilitates the formation of E-form products with high selectivity, demonstrating its versatility in photoredox transformations.

Refernces

Visible light-mediated dehydrogenative β-arylsulfonylation of tertiary aliphatic amines with arylsulfonyl chlorides

10.1039/c4ob01713g

The research focuses on the development of a green and efficient synthetic method for the novel synthesis of β-arylsulfonyl enamines through visible light-mediated dehydrogenative β-arylsulfonylation of tertiary aliphatic amines with arylsulfonyl chlorides. The purpose of this study was to explore the potential of photoredox catalysis in the synthesis of these enamines, leveraging the properties of Ru(bpy)3(PF6)2 as a photocatalyst under visible light irradiation. The researchers concluded that they had successfully developed a novel synthesis method for β-arylsulfonyl enamines, which was carried out in non-pretreated acetone open to air, and most reactions were completed within 10 minutes without any additives. Importantly, all products were obtained in the E-form. The chemicals used in the process included various arylsulfonyl chlorides, tertiary amines such as triethylamine, and Ru(bpy)3(PF6)2 as the photocatalyst.