1-(2-METHYLPHENYL)-2-NITROPROPENE

Base Information

• Chemical Name: 1-(2-METHYLPHENYL)-2-NITROPROPENE
• CAS No.: 147102-54-3
• Molecular Formula: C10H11NO2
• Molecular Weight: 177.2
• Mol file: 147102-54-3.mol

Synonyms:1-Methyl-2-[(1E)-2-nitro-1-propen-1-yl]benzene; benzene, 1-methyl-2-[(1E)-2-nitro-1-propen-1-yl]-

Chemical Property of 1-(2-METHYLPHENYL)-2-NITROPROPENE

Chemical Property:

• Vapor Pressure: 0.00807mmHg at 25°C
• Boiling Point: 276.5°C at 760 mmHg
• Flash Point: 119.2°C
• PSA: 45.82000
• Density: 1.112g/cm³
• LogP: 3.15570

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-(2-METHYLPHENYL)-2-NITROPROPENE

There total 3 articles about 1-(2-METHYLPHENYL)-2-NITROPROPENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

Nitroethane (79-24-3) + 2-methylphenyl aldehyde (529-20-4) → (E)-1-methyl-2-(2-nitroprop-1-enyl)benzene (147102-54-3)

Guidance literature:

With ammonium acetate; Heating;

DOI:10.1016/S0957-4166(01)00029-5

Reference yield: 84.0%

Nitroethane (79-24-3) + 2-methyl-benzyl alcohol (89-95-2) → (E)-1-methyl-2-(2-nitroprop-1-enyl)benzene (147102-54-3)

Guidance literature:

With but-2-enenitrile; carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II); piperdinium acetate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In toluene; for 8h; Inert atmosphere; Reflux;

DOI:10.1002/adsc.200800338

Reference yield:

Nitroethane (79-24-3) + 2-methylphenyl aldehyde (529-20-4) → 2-Nitro-1-(o-tolyl)-propen (103205-27-2,147102-54-3)

Guidance literature:

With ammonium acetate; In acetic acid;

DOI:10.1002/ardp.19923251203

upstream raw materials:

Nitroethane

2-methylphenyl aldehyde

2-methyl-benzyl alcohol

Downstream raw materials:

(E)-N-(1-O-tolylprop-1-en-2-yl)acetamide

(R)-N-(1-(o-tolyl)propan-2-yl)acetamide

1-(2'-methylphenyl)-2-nitropropane

1-(2-methylphenyl)acetone