1-(Phenylsulfonyl)indole-2-boronic acid MIDA ester, 1-(Phenylsulfonyl)indole-2-boronic acid, Methyliminodiacetic acid anhydride

Base Information

Chemical Name:1-(Phenylsulfonyl)indole-2-boronic acid MIDA ester, 1-(Phenylsulfonyl)indole-2-boronic acid, Methyliminodiacetic acid anhydride
CAS No.:1158984-95-2
Molecular Formula:C19H17BN2O6S
Molecular Weight:412.231
Hs Code.:
Mol file:1158984-95-2.mol

1-(Phenylsulfonyl)indole-2-boronic acid MIDA ester, 1-(Phenylsulfonyl)indole-2-boronic acid, Methyliminodiacetic acid anhydride

Synonyms:1-(Phenylsulfonyl)-2-indolylboronic acid MIDA ester;1-(Phenylsulfonyl)indole-2-boronic acid MIDA ester, 1-(Phenylsulfonyl)indole-2-boronic acid, Methyliminodiacetic acid anhydride;1-(Phenylsulfonyl)indole-2-boronic acid MIDA ester;1-(Phenylsulfonyl)indole-3-boronic acid MIDA ester;1-(Phenylsulfonyl)-2-indolylboronic acid MIDA ester 96%

Suppliers and Price of 1-(Phenylsulfonyl)indole-2-boronic acid MIDA ester, 1-(Phenylsulfonyl)indole-2-boronic acid, Methyliminodiacetic acid anhydride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
1-(Phenylsulfonyl)-2-indolylboronic acid MIDA ester 96%
5g
$ 252.00

American Custom Chemicals Corporation
1-(PHENYLSULFONYL)-2-INDOLYLBORONIC ACID MIDA ESTER 95.00%
1G
$ 733.11

Total 2 raw suppliers

Chemical Property of 1-(Phenylsulfonyl)indole-2-boronic acid MIDA ester, 1-(Phenylsulfonyl)indole-2-boronic acid, Methyliminodiacetic acid anhydride

Chemical Property:

Melting Point:159-165 °C
PSA：103.29000
LogP:1.62400

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-(Phenylsulfonyl)-2-indolylboronic acid MIDA ester 96% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses MIDA boronate for slow-release cross-couplingMIDA boronates as stable boronic acid surrogates for classically challenging cross-couplings.Suzuki Cross-Coupling with MIDA Boronates

Technology Process of 1-(Phenylsulfonyl)indole-2-boronic acid MIDA ester, 1-(Phenylsulfonyl)indole-2-boronic acid, Methyliminodiacetic acid anhydride

There total 1 articles about 1-(Phenylsulfonyl)indole-2-boronic acid MIDA ester, 1-(Phenylsulfonyl)indole-2-boronic acid, Methyliminodiacetic acid anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: (1-(phenylsulfonyl)-1H-indol-2-yl)boronic acid

: 4408-64-4
N-methyliminodiacetic acid

: 1158984-95-2
1-(phenylsulfonyl)-2-indole MIDA boronate

Guidance literature:: In dimethyl sulfoxide; toluene; for 3h; Reflux;

Reference yield: 100.0%

: potassium hydrogen bifluoride

: 1158984-95-2
1-(phenylsulfonyl)-2-indole MIDA boronate

: potassium trifluoro(1-(phenylsulfonyl)-1H-indol-2-yl)borate

Guidance literature:: In methanol; water; at 70 ℃; for 1.5h;
DOI:10.1021/acs.joc.5b00182

Reference yield: 97.0%

: 7051-13-0
1-chloro-2,4-dimethoxybenzene

: 1158984-95-2
1-(phenylsulfonyl)-2-indole MIDA boronate

: 1158985-11-5
N-phenylsulfonyl-2-(2,3-dimethoxyphenyl)indole

Guidance literature:: 1-chloro-2,4-dimethoxybenzene; 1-(phenylsulfonyl)-2-indole MIDA boronate; With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; In 1,4-dioxane; at 23 ℃; for 0.166667h; Inert atmosphere;

With potassium phosphate; water; In 1,4-dioxane; at 23 - 60 ℃; for 6.5h; Inert atmosphere;