4-Methyl-2,6,7-trioxabicyclo[2.2.2]octane

Base Information

Chemical Name:4-Methyl-2,6,7-trioxabicyclo[2.2.2]octane
CAS No.:766-32-5
Molecular Formula:C6H10O3
Molecular Weight:130.144
Hs Code.:
NSC Number:70107
DSSTox Substance ID:DTXSID30227405
Nikkaji Number:J694.887A
Wikidata:Q83107136

Synonyms:4-methyl-2,6,7-trioxabicyclo[2.2.2]octane;2,6,7-Trioxabicyclo(2.2.2)octane, 4-methyl-;766-32-5;4-Methyl-2,6,7-trioxabicyclo(2.2.2)octane;BRN 0105239;AI3-26911;NSC70107;5-19-09-00126 (Beilstein Handbook Reference);SCHEMBL2074745;DTXSID30227405;NSC 70107;NSC-70107;4-methyl-2,6,7-trioxa-bicyclo-[2,2,2]-octane

Suppliers and Price of 4-Methyl-2,6,7-trioxabicyclo[2.2.2]octane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 4-Methyl-2,6,7-trioxabicyclo[2.2.2]octane

Chemical Property:

Vapor Pressure:7.18mmHg at 25°C
Boiling Point:141.9°Cat760mmHg
Flash Point:43°C
Density:1.174g/cm³
XLogP3:0.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:130.062994177
Heavy Atom Count:9
Complexity:102

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC12COC(OC1)OC2

Technology Process of 4-Methyl-2,6,7-trioxabicyclo[2.2.2]octane

There total 2 articles about 4-Methyl-2,6,7-trioxabicyclo[2.2.2]octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 173729-54-9
(3-Methyloxetan-3-yl)methyl formate

: 766-32-5
4-Methyl-2,6,7-trioxabicyclo<2.2.2>octane

Guidance literature:: boron trifluoride diethyl etherate; In dichloromethane; for 24h; Ambient temperature;

Reference yield:

: 77-85-0
2-(hydroxymethyl)-2-methylpropane-1,3-diol

: 122-51-0
orthoformic acid triethyl ester

: 766-32-5
4-Methyl-2,6,7-trioxabicyclo<2.2.2>octane

Guidance literature:: DOI:10.1021/ja01608a001

Reference yield:

: 766-32-5
4-Methyl-2,6,7-trioxabicyclo<2.2.2>octane

: 76626-59-0
C₆H₉O₃

Guidance literature:: With di-tert-butyl peroxide; In dichloromethane; at -60 ℃; Irradiation; relative rate of hydrogen abstraction toward tert-butoxyl; stereoelectronic effects in this process was compared for a series of cyclic and acyclic ethers (for THF relative and absolute reactivities was determined);
DOI:10.1021/ja00393a018