1-(Bromomethyl)-4-methylidenecyclohexane

Base Information

Chemical Name:1-(Bromomethyl)-4-methylidenecyclohexane
CAS No.:76825-09-7
Molecular Formula:C8H13Br
Molecular Weight:189
Hs Code.:
DSSTox Substance ID:DTXSID70438871
Mol file:76825-09-7.mol

Synonyms:1-(bromomethyl)-4-methylidenecyclohexane;76825-09-7;DTXSID70438871;MFCD16710272;AKOS005765999;1-(Bromomethyl)-4-methylenecyclohexane;FE-0731;FT-0681983;J-503513

Suppliers and Price of 1-(Bromomethyl)-4-methylidenecyclohexane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
1-(Bromomethyl)-4-methylidenecyclohexane >95%
1g
$ 910.00

Matrix Scientific
1-(Bromomethyl)-4-methylidenecyclohexane >95%
500mg
$ 721.00

AK Scientific
1-(Bromomethyl)-4-methylidenecyclohexane
1g
$ 1278.00

AK Scientific
1-(Bromomethyl)-4-methylidenecyclohexane
500mg
$ 1023.00

Total 6 raw suppliers

Chemical Property of 1-(Bromomethyl)-4-methylidenecyclohexane

Chemical Property:

Boiling Point:65-66 °C(Press: 28 Torr)
Density:1.24±0.1 g/cm3(Predicted)
XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:188.02006
Heavy Atom Count:9
Complexity:97.1

Purity/Quality:

98%min ^*data from raw suppliers

1-(Bromomethyl)-4-methylidenecyclohexane >95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=C1CCC(CC1)CBr

Technology Process of 1-(Bromomethyl)-4-methylidenecyclohexane

There total 8 articles about 1-(Bromomethyl)-4-methylidenecyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 147151-51-7
1-<(Tosyloxy)methyl>-4-methylenecyclohexane

: 76825-09-7
(4-Methylenecyclohexylmethyl)bromide

Guidance literature:: With lithium bromide; In tetrahydrofuran; for 36h; Heating;
DOI:10.1021/jo00060a029

Reference yield:

: 120-47-8
Ethyl 4-hydroxybenzoate

: 76825-09-7
(4-Methylenecyclohexylmethyl)bromide

Guidance literature:: Multi-step reaction with 6 steps

1: 88 percent / H₂ / Raney nickel / ethanol / 48 h / 100 °C / 76000 Torr

2: 92 percent / Na₂Cr₂O₇, H₂SO₄ / diethyl ether; H₂O / 3 h

3: 1) NaH / 1) DMSO, 2 h, 80 deg C, 2) DMSO, 2 h, 50 deg C

4: 92 percent / LiAlH₄ / diethyl ether / 2 h / Heating

5: 95 percent / pyridine / 24 h / Ambient temperature

6: 72 percent / LiBr / tetrahydrofuran / 36 h / Heating

With pyridine; lithium aluminium tetrahydride; sodium dichromate; sulfuric acid; hydrogen; sodium hydride; lithium bromide; nickel; In tetrahydrofuran; diethyl ether; ethanol; water;
DOI:10.1021/jo00060a029

Reference yield:

: 1228182-62-4
Methanesulfonic acid 4-methylene-cyclohexylmethyl ester

: 76825-09-7
(4-Methylenecyclohexylmethyl)bromide

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium bromide; In acetone; for 6h; Yield given; Heating;
DOI:10.1021/jm00136a010