R-4-oxide-2,6-bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

Base Information

Chemical Name:R-4-oxide-2,6-bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
CAS No.:915038-16-3
Molecular Formula:C₃₂H₂₇Cl₂O₄P
Molecular Weight:577.444
Hs Code.:

Synonyms:R-4-oxide-2,6-bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bR)-2,6-Bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-oct ahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]d ioxaphosphepin

Suppliers and Price of R-4-oxide-2,6-bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Strem Chemicals
(11bR)-2,6-Bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98% (99% ee) 98% (99% ee)
50mg
$ 129.00

Total 8 raw suppliers

Chemical Property of R-4-oxide-2,6-bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

Chemical Property:

Melting Point:252-254 °C
Boiling Point:770.9±70.0 °C(Predicted)
PKA:1.12±0.20(Predicted)
Density:1.46±0.1 g/cm3(Predicted)

Purity/Quality:

98% ^*data from raw suppliers

(11bR)-2,6-Bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98% (99% ee) 98% (99% ee) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Useful:

Technology Process of R-4-oxide-2,6-bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

There total 2 articles about R-4-oxide-2,6-bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4-chloro-2,6-bis-(4-chloro-phenyl)-8,9,10,11,12,13,14,15-octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalene 4-oxide

: 915038-16-3
(R)-2,6-bis-(4-chloro-phenyl)-4-oxo-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-ol

Guidance literature:: With pyridine; In water; at 70 ℃; for 1h;
DOI:10.1021/ol062499t

Reference yield:

: 915038-18-5
(R)-3,3'-bis-(4-chlorophenyl)-5,5',6,6',7,7',8,8'-octahydro-[1,1']binaphthalenyl-2,2'-diol

: 915038-16-3
(R)-2,6-bis-(4-chloro-phenyl)-4-oxo-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-ol

Guidance literature:: Multi-step reaction with 2 steps

1: phosphorous oxychloride; pyridine / 5 h / 50 °C

2: pyridine / H₂O / 1 h / 70 °C

With pyridine; trichlorophosphate; In water;
DOI:10.1021/ol062499t