.beta.-D-erythro-Hex-3-enopyranose, 1,6-anhydro-3,4-dideoxy-, benzoate

Base Information

• Chemical Name: .beta.-D-erythro-Hex-3-enopyranose, 1,6-anhydro-3,4-dideoxy-, benzoate
• CAS No.: 67307-86-2
• Molecular Formula: C13H12O4
• Molecular Weight: 232.236
• Mol file: 67307-86-2.mol

Synonyms:.beta.-D-erythro-Hex-3-enopyranose, 1,6-anhydro-3,4-dideoxy-, benzoate

Chemical Property of .beta.-D-erythro-Hex-3-enopyranose, 1,6-anhydro-3,4-dideoxy-, benzoate

Chemical Property:

• PSA: 44.76000
• LogP: 1.52330

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of .beta.-D-erythro-Hex-3-enopyranose, 1,6-anhydro-3,4-dideoxy-, benzoate

There total 5 articles about .beta.-D-erythro-Hex-3-enopyranose, 1,6-anhydro-3,4-dideoxy-, benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.1%

1,6-anhydro-3,4-dideoxy-β-D-threo-hex-3-enopyranose (50705-28-7) + benzoic acid (65-85-0,8013-63-6) → 2-O-(benzoyl)-1,6-anhydro-3,4-dideoxy-β-D-erythro-hex-3-enopyranose (67307-86-2)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 48h; Ambient temperature;

DOI:10.3987/COM-91-5872

Reference yield: 74.9%

1,6-anhydro-3,4-dideoxy-β-D-threo-hex-3-enopyranose (50705-28-7) + triphenylphosphine (603-35-0) + diethylazodicarboxylate (1972-28-7,218603-74-8) → 2-O-(benzoyl)-1,6-anhydro-3,4-dideoxy-β-D-erythro-hex-3-enopyranose (67307-86-2)

Guidance literature:

With benzoic acid; In tetrahydrofuran; diethyl ether; hexane;

Reference yield: 50.0%

benzoic acid (65-85-0,8013-63-6) + 1,6-anhydro-3,4-dideoxy-β-D-threo/erythro-hex-3-enopyranose → 2-O-(benzoyl)-1,6-anhydro-3,4-dideoxy-β-D-erythro-hex-3-enopyranose (67307-86-2)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 20 ℃; for 48h;

DOI:10.1021/jo980436l

upstream raw materials:

1,6-anhydro-3,4-dideoxy-β-D-threo-hex-3-enopyranose

benzoic acid

levoglucosenone

triphenylphosphine

Downstream raw materials:

1,6-anhydro-β-D-galactopyranose

1,6-anhydro-β-D-glucopyranoside

1,6-anhydro-2-O-(tert-butyldiphenylsilyl)-3,4-dideoxy-β-D-erythro-hex-3-enopyranose

1,6-anhydro-2-O-(2,6-dichlorobenzoyl)-3,4-dideoxy-β-D-erythro-hex-3-enopyranose