Phenazine di-N-oxide

Base Information

• Chemical Name: Phenazine di-N-oxide
• CAS No.: 303-83-3
• Molecular Formula: C12H8 N2 O2
• Molecular Weight: 212.208
• European Community (EC) Number: 622-437-1
• NSC Number: 21666
• UNII: TJ2M8Y56UB
• DSSTox Substance ID: DTXSID20184391
• Nikkaji Number: J105.161J
• Wikidata: Q83055315
• ChEMBL ID: CHEMBL1971077
• Mol file: 303-83-3.mol

Synonyms:phenazine di-N-oxide

Chemical Property of Phenazine di-N-oxide

Chemical Property:

• Melting Point: 202-203 °C(Solv: ethanol (64-17-5))
• Boiling Point: °Cat760mmHg
• PKA: 0.55±0.30(Predicted)
• Flash Point: °C
• PSA: 50.92000
• Density: g/cm³
• LogP: 2.85000
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 212.058577502
• Heavy Atom Count: 16
• Complexity: 241

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)N(C3=CC=CC=C3[N+]2=O)[O-]

Technology Process of Phenazine di-N-oxide

There total 5 articles about Phenazine di-N-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Phenazin (92-82-0) → phenazine 5,10-dioxide (303-83-3)

Guidance literature:

With HOF* CH₃CN; In chloroform; at 0 ℃; for 0.666667h;

DOI:10.1021/jo0608016

Reference yield: 52.0%

Phenazin (92-82-0) → Phenazin-mono-N-Oxyd (304-81-4) + phenazine 5,10-dioxide (303-83-3)

Guidance literature:

With magnesium monoperoxyphthalate hexahydrate; In acetic acid; at 85 ℃; for 1h;

Reference yield:

→ phenazine 5,10-dioxide (303-83-3)

Guidance literature:

With benzene; substance of mp: 191 degree;

upstream raw materials:

Phenazin

Downstream raw materials:

Phenazin

Phenazin-mono-N-Oxyd

cyclohexanone

cyclohexanol

Refernces

• 1、 Greer, Melinda L.,Duncan, Joseph R.,Duff, Janice L.,Blackstock, Silas C.. "Solid-state complexes of quinoxaline- and phenazine-N,N'-dioxide donors with tetracyanoethylene. Crystal engineering via donor-acceptor interactions". . p. 7665 - 7668. Retrieved 1997.
• 2、 Carmeli, Mira,Rozen, Shlomo. "A new efficient route for the formation of quinoxaline N-oxides and N,N′-dioxides using HOF·CH3CN". . p. 5761 - 5765. Retrieved 2007/10/03.