3-broMo-3-ethylpentane

Base Information

• Chemical Name: 3-broMo-3-ethylpentane
• CAS No.: 73908-04-0
• Molecular Formula: C7H15Br
• Molecular Weight: 179.1
• Mol file: 73908-04-0.mol

Synonyms:3-broMo-3-ethylpentane

Chemical Property of 3-broMo-3-ethylpentane

Chemical Property:

• Boiling Point: 55 °C(Press: 15 Torr)
• PSA: 0.00000
• Density: 1.138±0.06 g/cm3(Predicted)
• LogP: 3.35010
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

98%min ^*data from raw suppliers

3-Bromo-3-ethylpentane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-broMo-3-ethylpentane

There total 3 articles about 3-broMo-3-ethylpentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

3-ethylpentan-3-ol (597-49-9) → triethylcarbinyl bromide (73908-04-0)

Guidance literature:

With trimethylsilyl bromide; In neat (no solvent); at 20 ℃; for 24h; chemoselective reaction; Green chemistry;

DOI:10.1016/j.tetlet.2016.04.083

Reference yield: 90.0%

2,2-diethylbutanoyl chloride (35354-15-5) → triethylcarbinyl bromide (73908-04-0)

Guidance literature:

With dmap; Bromotrichloromethane; 2-mercaptopyridine-1-oxide sodium salt; for 3h; Heating;

Reference yield:

1,1-diethyl-propylium (17603-21-3) + 1-(2-bromoethyl)-3-methylbenzene (16799-08-9) → triethylcarbinyl bromide (73908-04-0) + C9H11(1+)

Guidance literature:

at 26.85 ℃; Further Variations:; Reaction partners; Thermodynamic data; gas phase; low pressure;

DOI:10.1246/bcsj.71.1401

upstream raw materials:

3-ethylpentan-3-ol

2,2-diethylbutanoyl chloride

1,1-diethyl-propylium

1-(2-bromoethyl)-3-methylbenzene

Downstream raw materials:

3,3-Diaethyl-hexan

(3,3-diethylpent-1-yn-1-yl)benzene

4-ethylhexanoic acid

3-ethyl-2-pentene

Refernces

• 1、 Liu, Kwang-Ting,Hou, Su-Jiun,Tsao, Meng-Lin. "Nucleophilic solvent participation in the solvolysis of tertiary bromoalkanes". body text. p. 425 - 430. Retrieved 2009/12/24.
• 2、 Mustanir,Mishima, Masaaki,Fujio, Mizue,Tsuno, Yuho. "Thermodynamic Stabilities of Phenonium Ions Based on Bromide-Transfer Equilibria in the Gas Phase". . p. 1401 - 1407. Retrieved 2007/10/03.