(2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27,31-Octamethyldotriacontane-2,6,10,14,18,22,26,30-octene-1-ol

Base Information

• Chemical Name: (2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27,31-Octamethyldotriacontane-2,6,10,14,18,22,26,30-octene-1-ol
• CAS No.: 33569-79-8
• Molecular Formula: C40H66O
• Molecular Weight: 562.963
• Mol file: 33569-79-8.mol

Synonyms:(2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27,31-Octamethyl-2,6,10,14,18,22,26,30-dotriacontaocten-1-ol;(2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27,31-Octamethyldotriacontane-2,6,10,14,18,22,26,30-octene-1-ol;Farnesylfarnesylgeraniol

Chemical Property of (2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27,31-Octamethyldotriacontane-2,6,10,14,18,22,26,30-octene-1-ol

Chemical Property:

• PSA: 20.23000
• LogP: 13.03040

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27,31-Octamethyldotriacontane-2,6,10,14,18,22,26,30-octene-1-ol

There total 60 articles about (2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27,31-Octamethyldotriacontane-2,6,10,14,18,22,26,30-octene-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

C53H76OS (74629-78-0) → (E,E,E,E,E,E,E)-3,7,11,15,19,23,27,31-octamethyldotriaconta-2,6,10,14,18,22,26,30-octaen-1-ol (33569-79-8)

Guidance literature:

With lithium; ethylamine; In tetrahydrofuran; at -78 ℃; for 2h;

DOI:10.1021/jo01309a006

Reference yield: 71.5%

1-((2E,6E,10E,14Z,18E,22E,26E)-1-Benzyloxy-3,7,11,15,19,23,27,31-octamethyl-dotriaconta-2,6,10,14,18,22,26,30-octaene-9-sulfonyl)-4-methyl-benzene (68690-55-1,92542-08-0) → all-trans-3,7,11,15,19,23,27,31-octamethyl-2,6,10,14,18,22,26,30-triacontaoctaen-1-ol (5905-42-0,33569-79-8,120520-45-8,122170-91-6,138661-06-0,138661-07-1)

Guidance literature:

With lithium; ethylamine; In tetrahydrofuran; at -60 ℃; for 0.25h;

DOI:10.1246/bcsj.54.3530

Reference yield: 70.0%

(2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27,31-octamethyl-9-p-tolylsulphonyldotriaconta-2,6,10,14,18,22,26,30-octaen-1-ol → (E,E,E,E,E,E,E)-3,7,11,15,19,23,27,31-octamethyldotriaconta-2,6,10,14,18,22,26,30-octaen-1-ol (33569-79-8)

Guidance literature:

With lithium; ethylamine; In diethyl ether;

DOI:10.1039/P19810000761

upstream raw materials:

C₅₃H₇₆OS

(E,E,E,E,E,E,E)-1-(benzyloxy)-3,7,11,15,19,23,27,31-octamethyl-9-(phenylthio)dotriaconta-2,6,10,14,18,22,26,30-octaene

Geranylgeraniol

((2E,6E)-8-Bromo-3,7-dimethyl-octa-2,6-dienyloxymethyl)-benzene

Downstream raw materials:

1-methyl-4-{[(2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27,31-octamethyldotriaconta-2,6,10,14,18,22,26,30-octaen-1-yl]sulfonyl}benzene

Se-phenyl (E,E,E,E,E,E,E)-31-hydroxy-5,9,13,17,21,25,29-heptmethylhentriaconta-5,9,13,17,21,25,29-heptaeneselenoate

Se-phenyl (E,E,E,E,E,E,E)-5,9,13,17,21,25,29-heptamethyl-31-[(tetrahydro-2H-pyran-2-yl)oxy]hentriaconta-5,9,13,17,21,25,29-heptaeneselenoate

solanesol

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