Methyl 4-O,6-O-(phenylmethylene)-2,3-dideoxy-β-D-erythro-hexopyranoside

Base Information Edit

Chemical Name:Methyl 4-O,6-O-(phenylmethylene)-2,3-dideoxy-β-D-erythro-hexopyranoside
CAS No.:26532-08-1
Molecular Formula:C₁₄H₁₈O₄
Molecular Weight:250.295
Hs Code.:
Mol file:26532-08-1.mol

Synonyms:4,6-O-Benzyliden-2,3-didesoxy-methyl-β-D-glucopyranosid;Methyl-4,6-O-benzyliden-2,3-didesoxy-β-D-erythro-hexopyranosid;Methyl-2,3-anhydro-4,6-O-benzyliden-β-D-mannopyranosid;(4aR,6R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine;

Suppliers and Price of Methyl 4-O,6-O-(phenylmethylene)-2,3-dideoxy-β-D-erythro-hexopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl 4-O,6-O-(phenylmethylene)-2,3-dideoxy-β-D-erythro-hexopyranoside Edit

Chemical Property:

PSA：36.92000
LogP:2.25210

Purity/Quality:

Safty Information:

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Hazard Codes:

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Technology Process of Methyl 4-O,6-O-(phenylmethylene)-2,3-dideoxy-β-D-erythro-hexopyranoside

There total 7 articles about Methyl 4-O,6-O-(phenylmethylene)-2,3-dideoxy-β-D-erythro-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 1373344-40-1
C₂₁H₂₂O₆S

: 16848-76-3,26532-08-1,93237-54-8,117468-12-9,132074-92-1,132074-94-3,142632-74-4
methyl 4,6-O-benzylidene-2,3-dideoxy-α-D-galactopyranoside

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene; for 3h; Reflux;
DOI:10.1002/cjoc.201180487

Reference yield:

: 16848-76-3,26532-08-1,93237-54-8,117468-12-9,132074-92-1,132074-94-3,142632-74-4
methyl 4,6-O-benzylidene-2,3-dideoxy-α-D-galactopyranoside

Guidance literature:: With nickel; at 100 ℃; under 58840.6 Torr; Hydrogenation_.Behandlung des Reaktionsprodukts mit Benzaldehyd und Zinkchlorid;
DOI:10.1002/hlca.19480310627

Reference yield:

: 64552-06-3
methyl 4,6-O-benzylidene-α-D-galactopyranoside

: 16848-76-3,26532-08-1,93237-54-8,117468-12-9,132074-92-1,132074-94-3,142632-74-4
methyl 4,6-O-benzylidene-2,3-dideoxy-α-D-galactopyranoside

Guidance literature:: Multi-step reaction with 3 steps

2: 66 percent / tributyltin hydride / toluene / 14 h / Heating

3: 6.81 g / Raney nickel, ethyl acetate / 4 h

With tri-n-butyl-tin hydride; nickel; ethyl acetate; In toluene;