2,2-Dimethylpropyltrifluoroborate potassium salt

Base Information

• Chemical Name: 2,2-Dimethylpropyltrifluoroborate potassium salt
• CAS No.: 1150655-02-9
• Molecular Formula: C5H11BF3K
• Molecular Weight: 178.047
• Hs Code.: 2931900090
• Mol file: 1150655-02-9.mol

Synonyms:2,2-Dimethylpropyltrifluoroborate potassium salt;Potassium (2,2-dimethylprop-1-yl)trifluoroborate;Potassium trifluoro(neopentyl)borate

Chemical Property of 2,2-Dimethylpropyltrifluoroborate potassium salt

Chemical Property:

• PSA: 0.00000
• LogP: 2.87990
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

98% ^*data from raw suppliers

Potassium (2,2-dimethylprop-1-yl)trifluoroborate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2-Dimethylpropyltrifluoroborate potassium salt

There total 1 articles about 2,2-Dimethylpropyltrifluoroborate potassium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 2.2%

(CH3)3CCH2BF2 (237741-23-0) → hypercloso-B4(CH2(t)Bu)4 (237741-11-6) + potassium neopentyltrifluoroborate (1150655-02-9)

Guidance literature:

With Na/K alloy; In pentane; stirring for 2 h (spontaneous boling); filtration, washing of residue (pentane), evapn. of filtrates (vac.,), distn. (90°C, 0.001 mbar); K-salt from residue after filtration onextn. with THF;

DOI:10.1016/s0020-1693(99)00058-4

Reference yield: 97.0%

4-vinylpyridine (100-43-6,329041-72-7) + potassium neopentyltrifluoroborate (1150655-02-9) → 4-(2-(neopentylsulfonyl)ethyl)pyridine

Guidance literature:

With 1,4-diazabicyclo [2.2.2] octane-1,4-diium-1,4-disulfinate; 9-(2-mesityl)-10-methylacridinium perchlorate; In 1,2-dichloro-ethane; at 20 ℃; for 24h; Inert atmosphere; Irradiation;

DOI:10.1021/acs.orglett.8b01385

Reference yield: 79.0%

potassium neopentyltrifluoroborate (1150655-02-9) + benzyl 2-{bis[(tert-butoxy)carbonyl]amino}prop-2-enoate → C25H38FNO6

Guidance literature:

With 10-methyl-9-(2,4,6-trimethylphenyl) acridinium tetrafluoroborate; Selectfluor; In N,N-dimethyl-formamide; at 20 ℃; regioselective reaction; Irradiation;

DOI:10.1021/acscatal.8b04284

upstream raw materials:

(CH₃)3CCH₂BF₂

Downstream raw materials:

C₁₇H₂₁N

Refernces