6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline-1,2-diol

Base Information

Chemical Name:6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline-1,2-diol
CAS No.:3175-79-9
Molecular Formula:C17H17NO2
Molecular Weight:0
Hs Code.:
Mol file:3175-79-9.mol

Synonyms:(R)-5,6,6a,7-Tetrahydro-6-methyl-4H-dibenzo[de,g]quinoline-1,2-diol;6abeta-Aporphine-1,2-diol

Suppliers and Price of 6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline-1,2-diol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline-1,2-diol

Chemical Property:

Vapor Pressure:1.55E-09mmHg at 25°C
Boiling Point:472.1°C at 760 mmHg
Flash Point:267.6°C
Density:1.299g/cm³

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline-1,2-diol

There total 4 articles about 6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline-1,2-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 37082-15-8
(6aR)-2-methoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-1-ol

: 3175-79-9,50976-96-0
(6aR)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-1,2-diol

Guidance literature:: With aluminum tri-bromide; In acetonitrile; at 70 ℃; for 48h; Inert atmosphere;
DOI:10.1007/s00044-013-0905-9

Reference yield:

: (R)-1,2-Dimethoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline; hydriodide

: 3175-79-9,50976-96-0
(6aR)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-1,2-diol

Guidance literature:: With hydrogen iodide; In acetic anhydride;
DOI:10.1021/jm00269a602

Reference yield:

: 475-83-2,5868-18-8,16654-38-9,37659-75-9
R-(-)-nuciferine

: 3175-79-9,50976-96-0
(6aR)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-1,2-diol

Guidance literature:: Multi-step reaction with 2 steps

1: dibenzyl diselenide; sodium tetrahydroborate / N,N-dimethyl-formamide / Inert atmosphere; Reflux

2: aluminum tri-bromide / acetonitrile / 48 h / 70 °C / Inert atmosphere

With sodium tetrahydroborate; aluminum tri-bromide; dibenzyl diselenide; In N,N-dimethyl-formamide; acetonitrile;
DOI:10.1007/s00044-013-0905-9