4'' ,4'''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1''-terphenyl-4-amine)

Base Information

Chemical Name:4'' ,4'''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1''-terphenyl-4-amine)
CAS No.:1415633-86-1
Molecular Formula:C74H53N2OP
Molecular Weight:1017.22
Hs Code.:
Mol file:1415633-86-1.mol

Synonyms:4'' ,4'''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1''-terphenyl-4-amine)

Suppliers and Price of 4'' ,4'''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1''-terphenyl-4-amine)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of 4'' ,4'''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1''-terphenyl-4-amine)

Chemical Property:

Purity/Quality:: (Grade) > 98% (HPLC) ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of 4'' ,4'''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1''-terphenyl-4-amine)

There total 4 articles about 4'' ,4'''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1''-terphenyl-4-amine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 816421-98-4
4’-[1-naphthyl(phenyl)amino]biphenyl-4-ylboronic acid

: 93869-52-4
bis(4-bromophenyl)(phenyl)phosphine oxide

: 1415633-86-1
4’’,4’’’-(phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1’:4’,1’’-terphenyl-4-amine)

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In ethanol; toluene; at 100 ℃; for 48h; Inert atmosphere;
DOI:10.1002/chem.201201512

Reference yield:

: 644-97-3
Dichlorophenylphosphine

: 1415633-86-1
4’’,4’’’-(phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1’:4’,1’’-terphenyl-4-amine)

Guidance literature:: Multi-step reaction with 3 steps

1: n-butyllithium / hexane; tetrahydrofuran / 6 h / -78 °C

2: dihydrogen peroxide / dichloromethane / 20 °C

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / ethanol; toluene / 48 h / 100 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; dihydrogen peroxide; sodium carbonate; In tetrahydrofuran; ethanol; hexane; dichloromethane; toluene; 3: |Suzuki Coupling;
DOI:10.1002/chem.201201512

Reference yield:

: 84591-80-0
bis(4-bromophenyl)(phenyl)phosphine

: 1415633-86-1
4’’,4’’’-(phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1’:4’,1’’-terphenyl-4-amine)

Guidance literature:: Multi-step reaction with 2 steps

1: dihydrogen peroxide / dichloromethane / 20 °C

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / ethanol; toluene / 48 h / 100 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; dihydrogen peroxide; sodium carbonate; In ethanol; dichloromethane; toluene; 2: |Suzuki Coupling;
DOI:10.1002/chem.201201512