ETHYL 2-PHENYLBENZOYLFORMATE

Base Information

• Chemical Name: ETHYL 2-PHENYLBENZOYLFORMATE
• CAS No.: 947701-96-4
• Molecular Formula: C16H14O3
• Molecular Weight: 254.285
• Hs Code.: 2918300090
• Mol file: 947701-96-4.mol

Synonyms:ETHYL 2-PHENYLBENZOYLFORMATE

Chemical Property of ETHYL 2-PHENYLBENZOYLFORMATE

Chemical Property:

• Vapor Pressure: 1.1E-06mmHg at 25°C
• Boiling Point: 402.4°C at 760 mmHg
• Flash Point: 190°C
• PSA: 43.37000
• Density: 1.141g/cm³
• LogP: 3.09940

Purity/Quality:

99% ^*data from raw suppliers

Biphenyl-2-yloxoaceticacidethylester ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ETHYL 2-PHENYLBENZOYLFORMATE

There total 3 articles about ETHYL 2-PHENYLBENZOYLFORMATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

→ ethyl 2-([1,1'-biphenyl]-2-yl)-2-oxoacetate (947701-96-4)

Guidance literature:

Reference yield: 50.0%

2-Biphenylboronic acid (4688-76-0) + ethyl cyanoformate (623-49-4) → ethyl 2-([1,1'-biphenyl]-2-yl)-2-oxoacetate (947701-96-4)

Guidance literature:

With boric acid; [Rh(OH)(cod)]2; In 1,4-dioxane; at 60 ℃; for 3h;

DOI:10.1039/b704105e

Reference yield: 18.0%

2-Bromobiphenyl (2052-07-5) + oxalic acid diethyl ester (95-92-1) → ethyl 2-([1,1'-biphenyl]-2-yl)-2-oxoacetate (947701-96-4)

Guidance literature:

2-Bromobiphenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h;

oxalic acid diethyl ester; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h;

DOI:10.1016/j.ejmech.2018.11.004

upstream raw materials:

2-Biphenylboronic acid

ethyl cyanoformate

2-Bromobiphenyl

oxalic acid diethyl ester

Downstream raw materials:

C₂₇H₂₂N₂O₂