4-Fluoro-2-(methylthio)phenylboronic acid

Base Information

Chemical Name:4-Fluoro-2-(methylthio)phenylboronic acid
CAS No.:861931-38-6
Molecular Formula:C7H8BFO2S
Molecular Weight:186.015
Hs Code.:2931900090
DSSTox Substance ID:DTXSID60681733
Wikidata:Q82605870
Mol file:861931-38-6.mol

Synonyms:4-Fluoro-2-(methylthio)phenylboronic acid;861931-38-6;(4-fluoro-2-methylsulfanylphenyl)boronic acid;[4-Fluoro-2-(methylsulfanyl)phenyl]boronic acid;SCHEMBL1359056;DTXSID60681733;BAPCTRHEOVOYPW-UHFFFAOYSA-N;MFCD18087696;AKOS015853478;4-Fluoro-2-(methylthio)phenylboronicacid;BS-24077;CS-0163333;(4-fluoro-2-methylsulfanyl-phenyl)boronic acid;2-Methylsulfanyl-4-fluoro-benzene boronic acid;D94789

Suppliers and Price of 4-Fluoro-2-(methylthio)phenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-Fluoro-2-(methylthio)phenylboronicacid
50mg
$ 50.00

Ambeed
4-Fluoro-2-(methylthio)phenylboronicacid 98%
250mg
$ 126.00

Ambeed
4-Fluoro-2-(methylthio)phenylboronicacid 98%
100mg
$ 88.00

Ambeed
4-Fluoro-2-(methylthio)phenylboronicacid 98%
1g
$ 324.00

AK Scientific
4-Fluoro-2-(methylthio)phenylboronicacid
250mg
$ 211.00

Activate Scientific
4-Fluoro-2-(methylthio)phenylboronicacid 98%
250 mg
$ 207.00

Total 11 raw suppliers

Chemical Property of 4-Fluoro-2-(methylthio)phenylboronic acid

Chemical Property:

PSA：65.76000
LogP:0.22740
Storage Temp.:Room temperature.
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:186.0322090
Heavy Atom Count:12
Complexity:147

Purity/Quality:

97% ^*data from raw suppliers

4-Fluoro-2-(methylthio)phenylboronicacid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B(C1=C(C=C(C=C1)F)SC)(O)O

Technology Process of 4-Fluoro-2-(methylthio)phenylboronic acid

There total 1 articles about 4-Fluoro-2-(methylthio)phenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 147460-43-3
1-bromo-4-fluoro-2-(methylsulfanyl)benzene

: 861931-38-6
2-methylsulfanyl-4-fluoro-benzene boronic acid

Guidance literature:: 1-bromo-4-fluoro-2-(methylsulfanyl)benzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h;

With Trimethyl borate; at 20 ℃;

Reference yield: 83.0%

: 861931-38-6
2-methylsulfanyl-4-fluoro-benzene boronic acid

: 648905-79-7
trifluoro-methanesulfonic acid 6-methoxy-1-[4-(2-piperidin-1-yl-ethoxy)-benzoyl]-naphthalen-2-yl ester

: 861931-73-9
[2-(4-fluoro-2-methylsulfanyl-phenyl)-6-methoxy-naphthalen-1-yl]-[4-(2-piperidin-1-yl-ethoxy)-phenyl]-methanone

Guidance literature:: With cesium fluoride; tricyclohexylphosphine; palladium diacetate; In acetonitrile; at 80 ℃; for 0.5h;

Reference yield:

: 3934-20-1
2,6-Dichloropyrimidine

: 861931-38-6
2-methylsulfanyl-4-fluoro-benzene boronic acid

: 2-chloro-4-[4-fluoro-2-(methylthio)phenyl]pyrimidine

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In 1,2-dimethoxyethane; water; at 120 ℃; for 4h; Inert atmosphere;
DOI:10.1016/j.bmcl.2018.01.002