3,5-Dichlorophenyl methyl sulfoxide

Base Information

• Chemical Name: 3,5-Dichlorophenyl methyl sulfoxide
• CAS No.: 38452-22-1
• Molecular Formula: C7H6Cl2OS
• Molecular Weight: 209.0929
• Hs Code.: 2930909090
• Mol file: 38452-22-1.mol

Synonyms:DCMSO;3,5-dichlorophenyl methyl sulphoxide;3,5-Dichlorophenyl methyl sulfoxide;1,3-Dichloro-5-(methylsulfinyl)benzene;

Chemical Property of 3,5-Dichlorophenyl methyl sulfoxide

Chemical Property:

• Vapor Pressure: 6.92E-05mmHg at 25°C
• Boiling Point: 354.3°Cat760mmHg
• Flash Point: 168°C
• PSA: 36.28000
• Density: 1.5g/cm³
• LogP: 3.59650

Purity/Quality:

99%min ^*data from raw suppliers

3,5-Dichlorophenylmethylsulfoxide 90% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,5-Dichlorophenyl methyl sulfoxide

There total 3 articles about 3,5-Dichlorophenyl methyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(3,5-dichlorophenyl)(methyl)sulfane (68121-46-0) → 1,3-dichloro-5-(methylsulfinyl)benzene (38452-22-1)

Guidance literature:

With phthaloyl peroxide; In dichloromethane; at 25 ℃; for 8h; chemoselective reaction; Schlenk technique;

DOI:10.1039/c7ob00021a

Reference yield: 53.0%

→ 1,3-dichloro-5-(methylsulfinyl)benzene (38452-22-1)

Guidance literature:

With oxygen; lithium perchlorate; In N,N-dimethyl-formamide; at 25 ℃; for 3h; Electrochemical reaction;

Reference yield:

(3,5-dichlorophenyl)(methyl)sulfane (68121-46-0) → 1,3-dichloro-5-(methylsulfinyl)benzene + 1,3-dichloro-5-(methylsulfinyl)benzene (38452-22-1)

Guidance literature:

With hydroxy(phenyl)-λ³-iodanyl ((1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonate; In acetone; at -78 ℃; Reagent/catalyst; Overall yield = 83 percent; Optical yield = 5 percent ee;

DOI:10.1002/chem.202103623

upstream raw materials:

(3,5-dichlorophenyl)(methyl)sulfane

Downstream raw materials:

(3,5-dichlorophenyl)(methyl)sulfane

Refernces

• 1、 Amri, Nasser,Wirth, Thomas. "Flow Electrosynthesis of Sulfoxides, Sulfones, and Sulfoximines without Supporting Electrolytes". . p. 15961 - 15972. Retrieved 2021/07/20.
• 2、 -. "Synthesis method of sulfoxide compound". Paragraph 0031-0033; 0086-0088. . Retrieved 2021/04/07.