(-)-(3S,4R,5R)-3-(3',4'-methylenedioxybenzyl)-4-(3'',4''-dimethoxybenzyl)-5-(1-menthyloxy)butyrolactone

Base Information

Chemical Name:(-)-(3S,4R,5R)-3-(3',4'-methylenedioxybenzyl)-4-(3'',4''-dimethoxybenzyl)-5-(1-menthyloxy)butyrolactone
CAS No.:140138-38-1
Molecular Formula:C₃₁H₄₀O₇
Molecular Weight:524.654
Hs Code.:

Synonyms:(-)-(3S,4R,5R)-3-(3',4'-methylenedioxybenzyl)-4-(3'',4''-dimethoxybenzyl)-5-(1-menthyloxy)butyrolactone

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Chemical Property of (-)-(3S,4R,5R)-3-(3',4'-methylenedioxybenzyl)-4-(3'',4''-dimethoxybenzyl)-5-(1-menthyloxy)butyrolactone

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Technology Process of (-)-(3S,4R,5R)-3-(3',4'-methylenedioxybenzyl)-4-(3'',4''-dimethoxybenzyl)-5-(1-menthyloxy)butyrolactone

There total 5 articles about (-)-(3S,4R,5R)-3-(3',4'-methylenedioxybenzyl)-4-(3'',4''-dimethoxybenzyl)-5-(1-menthyloxy)butyrolactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 140138-36-9
(3R,4R,5R)-3-Benzo[1,3]dioxol-5-ylmethyl-4-[(3,4-dimethoxy-phenyl)-bis-phenylsulfanyl-methyl]-5-(2-isopropyl-5-methyl-cyclohexyloxy)-dihydro-furan-2-one

: 140138-38-1
(3R,4R,5R)-3-Benzo[1,3]dioxol-5-ylmethyl-4-(3,4-dimethoxy-benzyl)-5-(2-isopropyl-5-methyl-cyclohexyloxy)-dihydro-furan-2-one

Guidance literature:: With sodium tetrahydroborate; nickel dichloride;
DOI:10.1016/S0957-4166(00)80200-1

Reference yield: 99.0%

: 140138-36-9
(-)-(3S,4R,5R)-3-(3',4'-methylenedioxybenzyl)-4-<3'',4''-dimethoxy-α,α-bis(phenylthio)benzyl>-5-(1-menthyloxy)butyrolactone

: 140138-38-1
(-)-(3S,4R,5R)-3-(3',4'-methylenedioxybenzyl)-4-(3'',4''-dimethoxybenzyl)-5-(1-menthyloxy)butyrolactone

Guidance literature:: With sodium tetrahydroborate; nickel dichloride; In methanol; for 1h; Ambient temperature;

Reference yield:

: 60354-22-5
4-[Bis(phenylsulfanyl)methyl]-1,2-dimethoxybenzene

: 140138-38-1
(-)-(3S,4R,5R)-3-(3',4'-methylenedioxybenzyl)-4-(3'',4''-dimethoxybenzyl)-5-(1-menthyloxy)butyrolactone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) BuLi, 3.) DMI / 1) THF, hexane, -78 deg C, 3 h; 2) THF, hexane, -78 deg C, 2 h; 3) THF, hexane, -78 deg C --> room temperature, overnight

2: 99 percent / NiCl₂*6H₂O, NaBH₄ / methanol / 1 h / Ambient temperature

With sodium tetrahydroborate; n-butyllithium; desipramine; nickel dichloride; In methanol;