Ir(P(C₆H₅)3)2(C₆H₅CHCCH₃O)C₆H₅CH₂CHCCHCC₆H₅CH₂CH⁽¹⁺⁾*SbF₆^(1-)=Ir(P(C₆H₅)3)2(C₆H₅C₃HCH₃O)C₆H₅CH₂CHCHCC₆H₅CH₂CHSbF₆

Base Information

• Chemical Name: Ir(P(C₆H₅)3)2(C₆H₅CHCCH₃O)C₆H₅CH₂CHCCHCC₆H₅CH₂CH⁽¹⁺⁾*SbF₆^(1-)=Ir(P(C₆H₅)3)2(C₆H₅C₃HCH₃O)C₆H₅CH₂CHCHCC₆H₅CH₂CHSbF₆
• CAS No.: 515161-06-5
• Molecular Formula: C₆₄H₅₆IrOP₂*F₆Sb
• Molecular Weight: 1331.06

Synonyms:Ir(P(C₆H₅)3)2(C₆H₅CHCCH₃O)C₆H₅CH₂CHCCHCC₆H₅CH₂CH⁽¹⁺⁾*SbF₆^(1-)=Ir(P(C₆H₅)3)2(C₆H₅C₃HCH₃O)C₆H₅CH₂CHCHCC₆H₅CH₂CHSbF₆

Chemical Property of Ir(P(C₆H₅)3)2(C₆H₅CHCCH₃O)C₆H₅CH₂CHCCHCC₆H₅CH₂CH⁽¹⁺⁾*SbF₆^(1-)=Ir(P(C₆H₅)3)2(C₆H₅C₃HCH₃O)C₆H₅CH₂CHCHCC₆H₅CH₂CHSbF₆

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Technology Process of Ir(P(C₆H₅)3)2(C₆H₅CHCCH₃O)C₆H₅CH₂CHCCHCC₆H₅CH₂CH⁽¹⁺⁾*SbF₆^(1-)=Ir(P(C₆H₅)3)2(C₆H₅C₃HCH₃O)C₆H₅CH₂CHCHCC₆H₅CH₂CHSbF₆

There total 3 articles about Ir(P(C₆H₅)3)2(C₆H₅CHCCH₃O)C₆H₅CH₂CHCCHCC₆H₅CH₂CH⁽¹⁺⁾*SbF₆^(1-)=Ir(P(C₆H₅)3)2(C₆H₅C₃HCH₃O)C₆H₅CH₂CHCHCC₆H₅CH₂CHSbF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

trans-[IrH(PPh3)2(C(C6H5)=CHC(CH3)O)(acetone)]SbF6 (515160-93-7) + propargyl benzene (10147-11-2) → Ir(P(C6H5)3)2(C6H5CHCCH3O)C6H5CH2CHCCHCC6H5CH2CH(1+)*SbF6(1-)=Ir(P(C6H5)3)2(C6H5C3HCH3O)C6H5CH2CHCHCC6H5CH2CHSbF6 (515161-06-5)

Guidance literature:

In dichloromethane; 2 equiv id alkyne, CH2Cl2, 0°C, 1 h;

DOI:10.1021/ja0297281

Reference yield: 92.0%

trans-[IrH(PPh3)2(C(C6H5)=CHC(CH3)O)(acetone)]SbF6 (515160-93-7) + propargyl benzene (10147-11-2) → trans-bis(triphenylphosphine)(η2-(O,C1)-1-phenylbut-1-en-3-on-1-yl)(1,4-dibenzylbuta-1,4-dien-2-yl)iridium(III) hexafluoroantimonate (515161-06-5)

Guidance literature:

In dichloromethane; (Ar); alkyne (2 equiv.) was added via syringe to stirred soln. of Ir complex in CH2Cl2; soln. was stirred at room temp. for 2 h; concd. (vac.); Et2O added; washed (Et2O); filtered; dried (vac.); elem. anal.;

DOI:10.1021/om049271z

Reference yield:

trans-[IrH(PPh3)2(C(C6H5)=CHC(CH3)O)(acetone)]SbF6 (515160-93-7) + propargyl benzene (10147-11-2) + Phenylacetylene-d1 (3240-11-7) → trans-bis(triphenylphosphine)(η2-(O,C1)-1-phenylbut-1-en-3-on-1-yl)(1,4-dibenzylbuta-1,4-dien-2-yl)iridium(III) hexafluoroantimonate (515161-06-5) + [Ir(P(C6H5)3)2(C6H5CH2CHCHCCDC6H5)(C6H5CCHC(CH3)O)](1+)*SbF6(1-)=[Ir(P(C6H5)3)2(C6H5CH2CHCHCCDC6H5)(C6H5CCHC(CH3)O)]SbF6 (835890-13-6) + [Ir(P(C6H5)3)2(C6H5CDCHCCHCH2C6H5)(C6H5CCHC(CH3)O)](1+)*SbF6(1-)=[Ir(P(C6H5)3)2(C6H5CDCHCCHCH2C6H5)(C6H5CCHC(CH3)O)]SbF6 (835890-15-8) + trans-bis(triphenylphosphine)(η2-(O,C1)-1-phenylbut-1-en-3-on-1-yl)(1,4-diphenylbuta-1,4-dien-2-yl)iridium(III) hexafluoroantimonate (515161-04-3)

Guidance literature:

In dichloromethane; (Ar); mixt. of PhCCD and PhCH2CCH was added to stirred soln. of Ir complex in CH2Cl2 at room temp.; soln. was stirred for 48 h; volatiles removed (vac.); washed (pentane); dried (vac.); not isolated;

DOI:10.1021/om049271z

upstream raw materials:

trans-[IrH(PPh₃)2(C(C₆H₅)=CHC(CH₃)O)(acetone)]SbF₆

propargyl benzene

Phenylacetylene-d1

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