1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-hydroxymethyl-4-O-methyl-1,2,3,4-cyclohexantetrol

Base Information

Chemical Name:1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-hydroxymethyl-4-O-methyl-1,2,3,4-cyclohexantetrol
CAS No.:104976-46-7
Molecular Formula:C₂₄H₃₀O₆
Molecular Weight:414.499
Hs Code.:

Synonyms:1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-hydroxymethyl-4-O-methyl-1,2,3,4-cyclohexantetrol

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Chemical Property of 1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-hydroxymethyl-4-O-methyl-1,2,3,4-cyclohexantetrol

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Technology Process of 1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-hydroxymethyl-4-O-methyl-1,2,3,4-cyclohexantetrol

There total 1 articles about 1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-hydroxymethyl-4-O-methyl-1,2,3,4-cyclohexantetrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 104976-12-7
1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-4-O-methyl-1,2,3,4-cyclohexantetrol

: 104976-46-7
1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-hydroxymethyl-4-O-methyl-1,2,3,4-cyclohexantetrol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 6h; Ambient temperature;

Reference yield: 93.0%

: 3970-21-6
2-Methoxyethoxymethyl chloride

: 104976-46-7
1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-hydroxymethyl-4-O-methyl-1,2,3,4-cyclohexantetrol

: 104976-47-8
1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-<(2-methoxyethoxy)methoxymethyl>-4-O-methyl-1,2,3,4-cyclohexantetrol

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; for 20h; Ambient temperature;

Reference yield:

: 104976-46-7
1D-(1,2,4/3,5)-1-O-Acetyl-2,3-di-O-benzyl-5-C-hydroxymethyl-4-O-methyl-1,2,3,4-cyclohexantetrol

: 104976-52-5
(1R,2S,3R,4R,5R)-2-((1S,2R,3R,4R,5R)-2,3-Dihydroxy-5-hydroxymethyl-4-methoxy-cyclohexyloxy)-6,8-dioxa-bicyclo[3.2.1]octane-3,4-diol

Guidance literature:: Multi-step reaction with 6 steps

1: 93 percent / NEt(iPr)2 / CH₂Cl₂ / 20 h / Ambient temperature

2: 95 percent / NaOMe (1M) / methanol / 120 h / Ambient temperature

3: 1.) NaH / 1.) THF, 20 min, room temp.; 2.) THF, HMPA, 24 h, room temp.

4: 0.5M HCl / methanol / 12 h / Ambient temperature

5: pyridine / 12 h

6: H₂ / Pd/C (10percent) / methanol / 48 h / 22501.8 Torr

With pyridine; hydrogenchloride; hydrogen; sodium methylate; sodium hydride; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In methanol; dichloromethane;