phenyl 2-benzoxazolyl thioether

Base Information

• Chemical Name: phenyl 2-benzoxazolyl thioether
• CAS No.: 123773-64-8
• Molecular Formula: C₁₃H₉NOS
• Molecular Weight: 227.287
• Mol file: 123773-64-8.mol

Synonyms:phenyl 2-benzoxazolyl thioether

Chemical Property of phenyl 2-benzoxazolyl thioether

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl 2-benzoxazolyl thioether

There total 16 articles about phenyl 2-benzoxazolyl thioether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzoxazole (273-53-0,29791-96-6) + thiophenol (108-98-5) → phenyl 2-benzoxazolyl thioether (123773-64-8)

Guidance literature:

With (Tpr)CuI; potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 2h;

DOI:10.1016/j.tetlet.2013.06.104

Reference yield: 89.0%

phenylhydrazine hydrochloride (59-88-1) + 2-sulfanyl-1,3-benzoxazole (2382-96-9,118090-08-7) → phenyl 2-benzoxazolyl thioether (123773-64-8)

Guidance literature:

With rose bengal; sodium carbonate; In water; at 20 ℃; for 8h; Irradiation;

DOI:10.1021/acs.orglett.8b03549

Reference yield: 88.0%

bromobenzene (108-86-1,52753-63-6) + 2-sulfanyl-1,3-benzoxazole (2382-96-9,118090-08-7) → phenyl 2-benzoxazolyl thioether (123773-64-8)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 0.5h; Microwave irradiation;

DOI:10.1055/s-0033-1340501

upstream raw materials:

2-chloro-1,3-benzoxazole

sodium thiophenolate

benzoxazole

thiophenol

Downstream raw materials:

benzoxazole

1-phenyl-2-(phenylthio)propan-1-one

2-benzyl-1,3-benzoxazole

phenyl thiobenzoate

Refernces

• 1、 Ren, Xuanhe,Tang, Shanyu,Li, Longjia,Li, Jiao,Liang, Helong,Li, Ganzhong,Yang, Guanyu,Li, Heng,Yuan, Bingxin. "Surfactant-Type Catalyst for Aerobic Oxidative Coupling of Hydrazine with Thiol in Water". . p. 8683 - 8690. Retrieved 2019/07/08.
• 2、 Kibriya, Golam,Mondal, Susmita,Hajra, Alakananda. "Visible-Light-Mediated Synthesis of Unsymmetrical Diaryl Sulfides via Oxidative Coupling of Arylhydrazine with Thiol". supporting information. p. 7740 - 7743. Retrieved 2018/12/14.