(2S,3R,6S)-6-ethoxy-2-<(Z)-3'-methoxymethoxyprop-1'-enyl>-1-tosylpiperidin-3-ol

Base Information

Chemical Name:(2S,3R,6S)-6-ethoxy-2-<(Z)-3'-methoxymethoxyprop-1'-enyl>-1-tosylpiperidin-3-ol
CAS No.:162470-31-7
Molecular Formula:C₁₉H₂₉NO₆S
Molecular Weight:399.508
Hs Code.:

Synonyms:(2S,3R,6S)-6-ethoxy-2-<(Z)-3'-methoxymethoxyprop-1'-enyl>-1-tosylpiperidin-3-ol

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Chemical Property of (2S,3R,6S)-6-ethoxy-2-<(Z)-3'-methoxymethoxyprop-1'-enyl>-1-tosylpiperidin-3-ol

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Technology Process of (2S,3R,6S)-6-ethoxy-2-<(Z)-3'-methoxymethoxyprop-1'-enyl>-1-tosylpiperidin-3-ol

There total 6 articles about (2S,3R,6S)-6-ethoxy-2-<(Z)-3'-methoxymethoxyprop-1'-enyl>-1-tosylpiperidin-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 162470-30-6
(2S,6S)-6-ethoxy-2-<(Z)-3'-methoxymethoxyprop-1'-enyl>-1-tosyl-1,2,3,6-tetrahydropyridin-3-one

: 162470-31-7
(2S,3R,6S)-6-ethoxy-2-<(Z)-3'-methoxymethoxyprop-1'-enyl>-1-tosylpiperidin-3-ol

Guidance literature:: With sodium tetrahydroborate; In methanol; at -40 - -30 ℃;
DOI:10.1016/0040-4039(95)00058-K

Reference yield:

: 162470-28-2
N-<1-(2-furyl)-4-methoxymethoxybut-2-enyl>toluene-p-sulfonamide

: 162470-31-7
(2S,3R,6S)-6-ethoxy-2-<(Z)-3'-methoxymethoxyprop-1'-enyl>-1-tosylpiperidin-3-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 42 percent / Ti(OiPr)4, titanium(IV) isopropyl D-tartrate, calcium hydride, silica gel, tert-butyl hydroperoxide / CH₂Cl₂ / 72 h / 25 °C

2: 92 percent / BF₃*Et₂O, molecular sieves 4A / diethyl ether / Ambient temperature

3: 88 percent / sodium boranuide / methanol / 2 h / -40 - -30 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium tetrahydroborate; calcium hydride; 4 A molecular sieve; titanium(IV) isopropyl D-tartrate; boron trifluoride diethyl etherate; silica gel; In methanol; diethyl ether; dichloromethane;

Reference yield:

: 162470-29-3
(2S,6S)-6-hydroxy-2-(3-methoxymethoxyprop-1-enyl)-1-tosyl-1,2,3,6-tetrahydropyridin-3-one

: 162470-31-7
(2S,3R,6S)-6-ethoxy-2-<(Z)-3'-methoxymethoxyprop-1'-enyl>-1-tosylpiperidin-3-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / BF₃*Et₂O, molecular sieves 4A / diethyl ether / Ambient temperature

2: 88 percent / sodium boranuide / methanol / 2 h / -40 - -30 °C

With sodium tetrahydroborate; 4 A molecular sieve; boron trifluoride diethyl etherate; In methanol; diethyl ether;