C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3

Base Information

Chemical Name:C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3
CAS No.:82399-52-8
Molecular Formula:C₃₀H₂₇NOPRe
Molecular Weight:635.723
Hs Code.:

C<sub>5</sub>H<sub>5</sub>Re(NO)CH<sup>(2)</sup>HC<sub>6</sub>H<sub>5</sub>P(C<sub>6</sub>H<sub>5</sub>)3

Synonyms:C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3

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Chemical Property of C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3

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Technology Process of C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3

There total 2 articles about C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: lithium triethyl borodeuteride

: 74540-78-6
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

: 82399-52-8
C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3

Guidance literature:: In tetrahydrofuran; dichloromethane; Re-complex was dissolved in CH2Cl2, cooled to -78°C, ligand in THF was added dropwise under N2, after 15 min at -78°C soln. was allowed to warm to room temp., solvent was removed under vac.; residue extd. with benzene, filtered through silica gel, benzene was removed, recrystd. from CH2Cl2/hexane;
DOI:10.1021/ja00382a021

Reference yield:

: C₅H₅Re(NO)C⁽²⁾HC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)*CHCl₃=Re(NO)C₅H₅P(C₆H₅)3C₆H₅C⁽²⁾HPF₆*CHCl₃

: 22560-16-3
lithium triethylborohydride

: 82399-52-8
C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3

Guidance literature:: In dichloromethane; Re-complex in CH2Cl2 was reacted with ligand at -78°C under N2, soln. was warmed to room temp.; solvent was removed in vac., residue extd. with benzene, filtered through silica gel, benzene was removed, recrystd. from CH2Cl2/hexane;
DOI:10.1021/ja00382a021

Reference yield: 59.0%

: 82399-52-8
C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3

: 437-17-2
tritylium hexafluorophosphate

: 74561-64-1
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)*CHCl₃=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆*CHCl₃

Guidance literature:: In dichloromethane-d2; byproducts: Ph3CH; soln. of Re-complex in CD2Cl2 was cooled to -78°C, ligand in CD2Cl2 was added, tube was quickly transferred to -73°C NMR probe, warmed to room temp. for several h, applied silica gel TLC plate, eluted with ethyl acetate/hexanes; concd., residue recrystd. from hot EtOH, extd. with CH2Cl2, concd., residue recrystd. from CHCl3/petroleum ether;
DOI:10.1021/ja00382a021