MESO-TETRA(4-N,N,N-TRIMETHYLANILINIUM) PORPHINE TETRACHLORIDE

Base Information

• Chemical Name: MESO-TETRA(4-N,N,N-TRIMETHYLANILINIUM) PORPHINE TETRACHLORIDE
• CAS No.: 92739-64-5
• Molecular Formula: C₅₆H₆₂N₈*4Cl
• Molecular Weight: 988.974
• Mol file: 92739-64-5.mol

Synonyms:4,4',4,4'-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis tetrachloride

Chemical Property of MESO-TETRA(4-N,N,N-TRIMETHYLANILINIUM) PORPHINE TETRACHLORIDE

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

MEso-tetra(4-n,n,n-trimethylanilinium)porphinetetrachloride 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of MESO-TETRA(4-N,N,N-TRIMETHYLANILINIUM) PORPHINE TETRACHLORIDE

There total 1 articles about MESO-TETRA(4-N,N,N-TRIMETHYLANILINIUM) PORPHINE TETRACHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl p-toluene sulfonate (80-48-8) + N,N-dimethyl-4-[(5,10′,14′′,19′′′ )-10,15,20-tris(4-dimethylaminophenyl)-21,23-dihydroporphyrin-5-yl]aniline (14945-24-5) → 4,4',4,4'-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis tetrachloride (92739-64-5)

Guidance literature:

Multistep reaction; 1) N,N-dimethylformamide, 2) water, Dowex Model 1-X₈;

DOI:10.1021/j100368a082

Reference yield: 92.5%

4,4',4,4'-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis tetrachloride (92739-64-5) + water (7732-18-5) + trimethylaluminum (75-24-1) → C56H61AlN8O(4+)*4Cl(1-)

Guidance literature:

4,4',4",4'"-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis tetrachloride; trimethylaluminum; In hexane; dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

water; In hexane; dichloromethane; Inert atmosphere; Cooling with ice;

DOI:10.1246/bcsj.20150388

Reference yield: 92.0%

diammonium iron(II) sulfate hexahydrate + 4,4',4,4'-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis tetrachloride (92739-64-5) → Fe(5,10,15,20-tetrakis(N,N,N-trimethylanilinium-4-yl)porphyrinate)(5+) (96091-17-7)

Guidance literature:

diammonium iron(II) sulfate hexahydrate; 4,4',4",4'"-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis tetrachloride; In water; at 85 ℃; for 4h; Inert atmosphere;

With ammonium hexafluorophosphate;

DOI:10.1002/chem.202000160

upstream raw materials:

methyl p-toluene sulfonate

N,N-dimethyl-4-[(5,10′,14′′,19′′′ )-10,15,20-tris(4-dimethylaminophenyl)-21,23-dihydroporphyrin-5-yl]aniline

Downstream raw materials:

Fe(5,10,15,20-tetrakis(N,N,N-trimethylanilinium-4-yl)porphyrinate)⁽⁵⁺⁾