2-diphenyl-t-butylsiloxymethyl-6-methoxycarbonyl-3-oxabicyclo<3.3.0>octan-7-one

Base Information

Chemical Name:2-diphenyl-t-butylsiloxymethyl-6-methoxycarbonyl-3-oxabicyclo<3.3.0>octan-7-one
CAS No.:109917-95-5
Molecular Formula:C₂₆H₃₂O₅Si
Molecular Weight:452.623
Hs Code.:

Synonyms:2-diphenyl-t-butylsiloxymethyl-6-methoxycarbonyl-3-oxabicyclo<3.3.0>octan-7-one

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Chemical Property of 2-diphenyl-t-butylsiloxymethyl-6-methoxycarbonyl-3-oxabicyclo<3.3.0>octan-7-one

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Technology Process of 2-diphenyl-t-butylsiloxymethyl-6-methoxycarbonyl-3-oxabicyclo<3.3.0>octan-7-one

There total 10 articles about 2-diphenyl-t-butylsiloxymethyl-6-methoxycarbonyl-3-oxabicyclo<3.3.0>octan-7-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 99315-76-1
(5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone

: 109917-95-5
2-diphenyl-t-butylsiloxymethyl-6-methoxycarbonyl-3-oxabicyclo<3.3.0>octan-7-one

Guidance literature:: Multi-step reaction with 7 steps

1: 76 percent / aluminium chloride / CH₂Cl₂ / -5 - 60 °C

2: 9 g / lithium borohydride / tetrahydrofuran / 36 h / Ambient temperature

3: CH₂Cl₂; pyridine / 4 - 5 °C

4: 83 percent / CH₂Cl₂; pyridine / 0 °C

5: 100 percent / sodium periodate, kalium permanganate / acetone; H₂O / Ambient temperature

6: 80 percent / diethyl ether

7: potassium t-butoxide / benzene / 4 h / Ambient temperature

With potassium permanganate; sodium periodate; lithium borohydride; aluminium trichloride; potassium tert-butylate; In tetrahydrofuran; pyridine; diethyl ether; dichloromethane; water; acetone; benzene;

Reference yield:

: 99808-03-4
(1R,6S,7S)-7-diphenyl-t-butylsiloxymethyl-8-oxabicyclo-<4.3.0>non-3-ene

: 109917-95-5
2-diphenyl-t-butylsiloxymethyl-6-methoxycarbonyl-3-oxabicyclo<3.3.0>octan-7-one

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / sodium periodate, kalium permanganate / acetone; H₂O / Ambient temperature

2: 80 percent / diethyl ether

3: potassium t-butoxide / benzene / 4 h / Ambient temperature

With potassium permanganate; sodium periodate; potassium tert-butylate; In diethyl ether; water; acetone; benzene;

Reference yield:

: 99315-77-2
(4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene

: 109917-95-5
2-diphenyl-t-butylsiloxymethyl-6-methoxycarbonyl-3-oxabicyclo<3.3.0>octan-7-one

Guidance literature:: Multi-step reaction with 5 steps

1: CH₂Cl₂; pyridine / 4 - 5 °C

2: 83 percent / CH₂Cl₂; pyridine / 0 °C

3: 100 percent / sodium periodate, kalium permanganate / acetone; H₂O / Ambient temperature

4: 80 percent / diethyl ether

5: potassium t-butoxide / benzene / 4 h / Ambient temperature

With potassium permanganate; sodium periodate; potassium tert-butylate; In pyridine; diethyl ether; dichloromethane; water; acetone; benzene;