(1R,2R)-2-((R)-3,3-diethyl-14,14-dimethyl-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecan-5-yl)-N-methoxy-N-methylcyclopropanecarboxamide

Base Information

Chemical Name:(1R,2R)-2-((R)-3,3-diethyl-14,14-dimethyl-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecan-5-yl)-N-methoxy-N-methylcyclopropanecarboxamide
CAS No.:1293981-37-9
Molecular Formula:C₃₅H₅₇NO₄Si₂
Molecular Weight:612.013
Hs Code.:

Synonyms:(1R,2R)-2-((R)-3,3-diethyl-14,14-dimethyl-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecan-5-yl)-N-methoxy-N-methylcyclopropanecarboxamide

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Chemical Property of (1R,2R)-2-((R)-3,3-diethyl-14,14-dimethyl-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecan-5-yl)-N-methoxy-N-methylcyclopropanecarboxamide

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Technology Process of (1R,2R)-2-((R)-3,3-diethyl-14,14-dimethyl-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecan-5-yl)-N-methoxy-N-methylcyclopropanecarboxamide

There total 8 articles about (1R,2R)-2-((R)-3,3-diethyl-14,14-dimethyl-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecan-5-yl)-N-methoxy-N-methylcyclopropanecarboxamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1293981-32-4
(1R,2R)-2-((R)-7-(tert-butyldiphenylsilyloxy)-1-hydroxyheptyl)-N-methoxy-N-methylcyclopropanecarboxamide

: 79271-56-0
triethylsilyl trifluoromethyl sulfonate

: 1293981-37-9
(1R,2R)-2-((R)-3,3-diethyl-14,14-dimethyl-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecan-5-yl)-N-methoxy-N-methylcyclopropanecarboxamide

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 ℃; Inert atmosphere;
DOI:10.1016/j.tetlet.2011.02.008

Reference yield:

: 1293981-48-2
9-(tert-butyldiphenylsilyloxy)non-1-en-3-ol

: 1293981-37-9
(1R,2R)-2-((R)-3,3-diethyl-14,14-dimethyl-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecan-5-yl)-N-methoxy-N-methylcyclopropanecarboxamide

Guidance literature:: Multi-step reaction with 4 steps

1: 2-iodoxybenzoic acid / tetrahydrofuran; dimethyl sulfoxide / 3 h / 20 °C / Inert atmosphere

2: hydroquinine-2,5-diphenyl-4,6-pyrimidinediyl diether; caesium carbonate / acetonitrile / 24 h / 80 °C / Inert atmosphere

3: C₁₀H₁₄*C₁₄H₁₄N₂RuS; potassium carbonate; isopropyl alcohol / dichloromethane / 6 h / 80 °C / Inert atmosphere

4: 2,6-dimethylpyridine / dichloromethane / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; 2-iodoxybenzoic acid; C₁₀H₁₄*C₁₄H₁₄N₂RuS; hydroquinine-2,5-diphenyl-4,6-pyrimidinediyl diether; potassium carbonate; caesium carbonate; isopropyl alcohol; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; acetonitrile;
DOI:10.1016/j.tetlet.2011.02.008

Reference yield:

: 1293981-33-5
9-(tert-butyldiphenylsilyloxy)non-1-en-3-one

: 1293981-37-9
(1R,2R)-2-((R)-3,3-diethyl-14,14-dimethyl-13,13-diphenyl-4,12-dioxa-3,13-disilapentadecan-5-yl)-N-methoxy-N-methylcyclopropanecarboxamide

Guidance literature:: Multi-step reaction with 3 steps

1: hydroquinine-2,5-diphenyl-4,6-pyrimidinediyl diether; caesium carbonate / acetonitrile / 24 h / 80 °C / Inert atmosphere

2: C₁₀H₁₄*C₁₄H₁₄N₂RuS; potassium carbonate; isopropyl alcohol / dichloromethane / 6 h / 80 °C / Inert atmosphere

3: 2,6-dimethylpyridine / dichloromethane / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; C₁₀H₁₄*C₁₄H₁₄N₂RuS; hydroquinine-2,5-diphenyl-4,6-pyrimidinediyl diether; potassium carbonate; caesium carbonate; isopropyl alcohol; In dichloromethane; acetonitrile;
DOI:10.1016/j.tetlet.2011.02.008