(S,S)-1,8-bis(diphenylphosphinyl)-9,16-bis(trifluoromethanesulfonyloxy)tetraphenylene

Base Information

Chemical Name:(S,S)-1,8-bis(diphenylphosphinyl)-9,16-bis(trifluoromethanesulfonyloxy)tetraphenylene
CAS No.:862015-15-4
Molecular Formula:C₅₀H₃₂F₆O₈P₂S₂
Molecular Weight:1000.87
Hs Code.:

Synonyms:(S,S)-1,8-bis(diphenylphosphinyl)-9,16-bis(trifluoromethanesulfonyloxy)tetraphenylene

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Chemical Property of (S,S)-1,8-bis(diphenylphosphinyl)-9,16-bis(trifluoromethanesulfonyloxy)tetraphenylene

Chemical Property:

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Technology Process of (S,S)-1,8-bis(diphenylphosphinyl)-9,16-bis(trifluoromethanesulfonyloxy)tetraphenylene

There total 1 articles about (S,S)-1,8-bis(diphenylphosphinyl)-9,16-bis(trifluoromethanesulfonyloxy)tetraphenylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 862015-14-3
(S,S)-1,8,9,16-tetra(trifluoromethanesulfonyloxy)tetraphenylene

: 4559-70-0
Diphenylphosphine oxide

: 862015-15-4
(S,S)-1,8-bis(diphenylphosphinyl)-9,16-bis(trifluoromethanesulfonyloxy)tetraphenylene

Guidance literature:: With palladium diacetate; 1,3-bis-(diphenylphosphino)propane; N-ethyl-N,N-diisopropylamine; In dimethyl sulfoxide; at 100 ℃; for 24h;
DOI:10.1021/ja051013l

Reference yield:

: 862015-15-4
(S,S)-1,8-bis(diphenylphosphinyl)-9,16-bis(trifluoromethanesulfonyloxy)tetraphenylene

: (S,S)-1,8,9,16-tetrakis(diphenylphosphino)tetraphenylene

Guidance literature:: Multi-step reaction with 3 steps

1: PhNMe₂; HSiCl₃ / toluene / 24 h / 100 °C

2: Pd(OAc)2; 1,3-bis(diphenylphosphino)butane; diisopropylethylamine / dimethylsulfoxide / 14 h / 100 °C

3: Et₃N; HSiCl₃ / toluene / 24 h / 100 °C

With palladium diacetate; trichlorosilane; N,N-dimethyl-aniline; triethylamine; N-ethyl-N,N-diisopropylamine; 1,3-bis(diphenylphosphanyl)butane; In dimethyl sulfoxide; toluene;
DOI:10.1021/ja051013l

Reference yield:

: 862015-15-4
(S,S)-1,8-bis(diphenylphosphinyl)-9,16-bis(trifluoromethanesulfonyloxy)tetraphenylene

: 862015-17-6,862015-19-8
(S,S)-1,8,9,16-tetrakis(diphenylphosphinyl)tetraphenylene

Guidance literature:: Multi-step reaction with 2 steps

1: PhNMe₂; HSiCl₃ / toluene / 24 h / 100 °C

2: Pd(OAc)2; 1,3-bis(diphenylphosphino)butane; diisopropylethylamine / dimethylsulfoxide / 14 h / 100 °C

With palladium diacetate; trichlorosilane; N,N-dimethyl-aniline; N-ethyl-N,N-diisopropylamine; 1,3-bis(diphenylphosphanyl)butane; In dimethyl sulfoxide; toluene;
DOI:10.1021/ja051013l