(R)-(E)-3-methyl-3-styrylcyclohexanone

Base Information

Chemical Name:(R)-(E)-3-methyl-3-styrylcyclohexanone
CAS No.:1244782-88-4
Molecular Formula:C₁₅H₁₈O
Molecular Weight:214.307
Hs Code.:

Synonyms:(R)-(E)-3-methyl-3-styrylcyclohexanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-(E)-3-methyl-3-styrylcyclohexanone

Chemical Property:

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Technology Process of (R)-(E)-3-methyl-3-styrylcyclohexanone

There total 6 articles about (R)-(E)-3-methyl-3-styrylcyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 1193-18-6
3-methylcyclohexen-2-one

: 588-72-7,1340-14-3
[(E)-2-bromoethenyl]benzene

: 1244782-88-4
(R)-(E)-3-methyl-3-styrylcyclohexanone

Guidance literature:: [(E)-2-bromoethenyl]benzene; With tert.-butyl lithium; In tert-butyl methyl ether; pentane; at -78 ℃; for 0.5h; Inert atmosphere;

With dimethylaluminum chloride; In n-heptane; tert-butyl methyl ether; pentane; at -78 - 20 ℃; Inert atmosphere;

3-methylcyclohexen-2-one; optical yield given as %ee; enantioselective reaction; Further stages;
DOI:10.1055/s-0029-1219958

Reference yield: 64.0%

: 1193-18-6
3-methylcyclohexen-2-one

: 1365919-22-7,852635-58-6
(E)-dimethyl(styryl)aluminum

: 1244782-88-4
(R)-(E)-3-methyl-3-styrylcyclohexanone

Guidance literature:: (E)-dimethyl(styryl)aluminum; With copper(I) thiophene-2-carboxylate; 1,1-bis(3,5-dimethylphenyl)-N,N-bis((S)-1-(naphthalen-2-yl)ethyl)phosphinamine; In diethyl ether; at -30 ℃; for 0.25h; Inert atmosphere;

3-methylcyclohexen-2-one; In diethyl ether; at -30 ℃; for 14h; enantioselective reaction; Inert atmosphere;
DOI:10.1002/chem.201302856

Reference yield:

: 1193-18-6
3-methylcyclohexen-2-one

: 67826-86-2,123364-21-6
(E)-diisobutyl(styryl)aluminum

: 1244782-88-4
(R)-(E)-3-methyl-3-styrylcyclohexanone

: C₁₅H₁₈O

: (S)-(E)-3-methyl-3-styrylcyclohexanone

Guidance literature:: With 1,1-bis(3,5-dimethylphenyl)-N,N-bis((S)-1-(naphthalen-2-yl)ethyl)phosphinamine; trimethylaluminum; copper(II) β-naphthoate; In diethyl ether; n-heptane; pentane; at -30 - -20 ℃; for 14h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol200898c