2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]iodoethane

Base Information

Chemical Name:2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]iodoethane
CAS No.:866223-63-4
Molecular Formula:C₁₇H₃₃IOSi
Molecular Weight:408.438
Hs Code.:

Synonyms:2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]iodoethane

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Chemical Property of 2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]iodoethane

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Technology Process of 2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]iodoethane

There total 2 articles about 2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]iodoethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Toluene-4-sulfonic acid 2-[(1R,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-6-methylene-cyclohexyl]-ethyl ester

: 866223-63-4
2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]iodoethane

Guidance literature:: With sodium iodide; In acetone; for 4h; Heating;
DOI:10.1016/j.tet.2005.06.115

Reference yield:

: 124177-10-2
(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylenecyclohexaneethanol

: 866223-63-4
2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]iodoethane

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / 4 °C

2: 923 mg / NaI / acetone / 4 h / Heating

With pyridine; sodium iodide; In acetone;
DOI:10.1016/j.tet.2005.06.115

Reference yield: 50.0%

: 91270-71-2
6-bromo-1,4-dimethoxynaphthalene

: 866223-63-4
2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]iodoethane

: tert-Butyl-((1S,3R)-3-ethyl-2,2-dimethyl-4-methylene-cyclohexyloxy)-dimethyl-silane

: 866223-64-5
6-{2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]ethyl}-1,4-dimethoxynaphthalene

Guidance literature:: 2-[(1R,3S)-3-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6-methylidenecyclohexyl]iodoethane; With tert.-butyl lithium; 9-methoxy-9-BBN; In various solvents; at -78 - 20 ℃; for 1.41667h;

6-bromo-1,4-dimethoxynaphthalene; With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In various solvents; at 80 ℃; for 16h;
DOI:10.1016/j.tet.2005.06.115