(R)-4-((2S,3R)-3-(tert-butyldiphenylsilyloxy)-2,3-dihydrofuran-2-yl)-2,2-dimethyl-1,3-dioxolane

Base Information

Chemical Name:(R)-4-((2S,3R)-3-(tert-butyldiphenylsilyloxy)-2,3-dihydrofuran-2-yl)-2,2-dimethyl-1,3-dioxolane
CAS No.:153984-58-8
Molecular Formula:C₂₅H₃₂O₄Si
Molecular Weight:424.612
Hs Code.:

Synonyms:(R)-4-((2S,3R)-3-(tert-butyldiphenylsilyloxy)-2,3-dihydrofuran-2-yl)-2,2-dimethyl-1,3-dioxolane

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Chemical Property of (R)-4-((2S,3R)-3-(tert-butyldiphenylsilyloxy)-2,3-dihydrofuran-2-yl)-2,2-dimethyl-1,3-dioxolane

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Technology Process of (R)-4-((2S,3R)-3-(tert-butyldiphenylsilyloxy)-2,3-dihydrofuran-2-yl)-2,2-dimethyl-1,3-dioxolane

There total 1 articles about (R)-4-((2S,3R)-3-(tert-butyldiphenylsilyloxy)-2,3-dihydrofuran-2-yl)-2,2-dimethyl-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67222-87-1
phenyl 2,3;5,6-di-O-isopropylidene-1-thio-β-D-mannofuranoside

: 58479-61-1
tert-butylchlorodiphenylsilane

: 153984-58-8
(R)-4-((2S,3R)-3-(tert-butyldiphenylsilyloxy)-2,3-dihydrofuran-2-yl)-2,2-dimethyl-1,3-dioxolane

Guidance literature:: With potassium; pyrographite; Yield given. Multistep reaction; 1.) THF, 10 min, 2.) r.t., 30 min;

Reference yield: 95.0%

: 153984-58-8
(R)-4-((2S,3R)-3-(tert-butyldiphenylsilyloxy)-2,3-dihydrofuran-2-yl)-2,2-dimethyl-1,3-dioxolane

: 195066-37-6
tert-Butyl-[(1S,3R,4S,5R)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,6-dioxa-bicyclo[3.1.0]hex-4-yloxy]-diphenyl-silane

Guidance literature:: With 3,3-dimethyldioxirane; In dichloromethane; acetone; at 0 ℃; for 0.0833333h;
DOI:10.1055/s-1997-5756

Reference yield:

: 153984-58-8
(R)-4-((2S,3R)-3-(tert-butyldiphenylsilyloxy)-2,3-dihydrofuran-2-yl)-2,2-dimethyl-1,3-dioxolane

: N-[(4R,5R)-4-(tert-Butyl-diphenyl-silanyloxy)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-oxo-tetrahydro-furan-3-yl]-2,2,2-trifluoro-acetamide

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) nitridomanganese(V), 2.) silica gel / 1.) CH₂Cl₂, -78 -> 23 deg C, 2.) other reagent: H₃O⁽¹⁺⁾

2: pyridinium chlorochromate / CH₂Cl₂

With nitridomanganese(V); silica gel; pyridinium chlorochromate; In dichloromethane;
DOI:10.1021/ja964381l