(E)-m-bromo-p-methoxycinnamyl (E)-cinnamyl ether

Base Information

• Chemical Name: (E)-m-bromo-p-methoxycinnamyl (E)-cinnamyl ether
• CAS No.: 1234462-60-2
• Molecular Formula: C₁₉H₁₉BrO₂
• Molecular Weight: 359.263
• Mol file: 1234462-60-2.mol

Synonyms:(E)-m-bromo-p-methoxycinnamyl (E)-cinnamyl ether

Chemical Property of (E)-m-bromo-p-methoxycinnamyl (E)-cinnamyl ether

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-m-bromo-p-methoxycinnamyl (E)-cinnamyl ether

There total 1 articles about (E)-m-bromo-p-methoxycinnamyl (E)-cinnamyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

(E)-3-(m-bromo-p-methoxyphenyl)-2-propen-1-ol (1234462-90-8) + Cinnamyl bromide (4392-24-9) → (E)-m-bromo-p-methoxycinnamyl (E)-cinnamyl ether (1234462-60-2)

Guidance literature:

(E)-3-(m-bromo-p-methoxyphenyl)-2-propen-1-ol; With sodium hydride; In tetrahydrofuran; mineral oil; at 20 ℃; for 0.5h;

Cinnamyl bromide; In tetrahydrofuran; mineral oil; at 0 - 20 ℃;

DOI:10.1021/ja103934y

Reference yield: 71.0%

(E)-m-bromo-p-methoxycinnamyl (E)-cinnamyl ether (1234462-60-2) → (1R*,5S*,6R*,7S*)-7-(m-bromo-p-methoxyphenyl)-6-phenyl-3-oxabicyclo[3.2.0]heptane

Guidance literature:

With tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; magnesium sulfate; N,N'-dimethyl-4,4'-bipyridinium dihexafluorophosphate; In nitromethane; for 7.5h; optical yield given as %de; Inert atmosphere; Irradiation;

DOI:10.1021/ja103934y

Reference yield:

(E)-m-bromo-p-methoxycinnamyl (E)-cinnamyl ether (1234462-60-2) → C19H19BrO4 + C19H19BrO4

Guidance literature:

With Ru(bpz)₃(PF₆)₂; oxygen; In nitromethane; at 5 ℃; for 12h; under 3102.97 Torr; optical yield given as %de; diastereoselective reaction; Irradiation;

DOI:10.1021/ol300428q

upstream raw materials:

(E)-3-(m-bromo-p-methoxyphenyl)-2-propen-1-ol

Cinnamyl bromide