zinc(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)-2-(4-carboxyphenylethynyl)porphyrin

Base Information

• Chemical Name: zinc(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)-2-(4-carboxyphenylethynyl)porphyrin
• CAS No.: 1138342-05-8
• Molecular Formula: C₈₅H₉₆N₄O₂Zn
• Molecular Weight: 1271.11
• Mol file: 1138342-05-8.mol

Synonyms:zinc(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)-2-(4-carboxyphenylethynyl)porphyrin

Chemical Property of zinc(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)-2-(4-carboxyphenylethynyl)porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zinc(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)-2-(4-carboxyphenylethynyl)porphyrin

There total 2 articles about zinc(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)-2-(4-carboxyphenylethynyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

4-Ethynyl-benzoic acid (10602-00-3) + 1-bromo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrin (1138342-10-5) → [2-(4'-carboxyphenylethynyl)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinate]ZnII (1138342-05-8)

Guidance literature:

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; diethylamine; In N,N-dimethyl-formamide; at -78 - 120 ℃; for 1h; Schlenk technique; Inert atmosphere; Microwave irradiation;

DOI:10.1002/chem.201300219

Reference yield: 30.0%

zinc(II) 2-bromo-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin (1138342-10-5) + 4-Ethynyl-benzoic acid (10602-00-3) → zinc(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)-2-(4-carboxyphenylethynyl)porphyrin (1138342-05-8)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; triphenyl-arsane; triethylamine; In tetrahydrofuran; Reflux; Inert atmosphere;

DOI:10.1002/chem.200801572

upstream raw materials:

zinc(II) 2-bromo-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

4-Ethynyl-benzoic acid

1-bromo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrin