6a-Benzenesulfonyl-4-chloromethyl-5-trimethylsilanylmethyl-2,3,6,6a-tetrahydro-1H-pentalen-3a-ol

Base Information

Chemical Name:6a-Benzenesulfonyl-4-chloromethyl-5-trimethylsilanylmethyl-2,3,6,6a-tetrahydro-1H-pentalen-3a-ol
CAS No.:127358-60-5
Molecular Formula:C₁₉H₂₇ClO₃SSi
Molecular Weight:399.026
Hs Code.:

Synonyms:6a-Benzenesulfonyl-4-chloromethyl-5-trimethylsilanylmethyl-2,3,6,6a-tetrahydro-1H-pentalen-3a-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 6a-Benzenesulfonyl-4-chloromethyl-5-trimethylsilanylmethyl-2,3,6,6a-tetrahydro-1H-pentalen-3a-ol

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Technology Process of 6a-Benzenesulfonyl-4-chloromethyl-5-trimethylsilanylmethyl-2,3,6,6a-tetrahydro-1H-pentalen-3a-ol

There total 3 articles about 6a-Benzenesulfonyl-4-chloromethyl-5-trimethylsilanylmethyl-2,3,6,6a-tetrahydro-1H-pentalen-3a-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 127358-50-3
Methanesulfonic acid 2-trimethylsilanylmethyl-buta-2,3-dienyl ester

: 127358-60-5
6a-Benzenesulfonyl-4-chloromethyl-5-trimethylsilanylmethyl-2,3,6,6a-tetrahydro-1H-pentalen-3a-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / sodium iodide / dimethylformamide / 60 °C

2: dimethylaluminum chloride / CH₂Cl₂; diethyl ether / Ambient temperature

With dimethylaluminum chloride; sodium iodide; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00168a065

Reference yield:

: C₁₁H₁₁NaO₃S

: 127358-60-5
6a-Benzenesulfonyl-4-chloromethyl-5-trimethylsilanylmethyl-2,3,6,6a-tetrahydro-1H-pentalen-3a-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / sodium iodide / dimethylformamide / 60 °C

2: dimethylaluminum chloride / CH₂Cl₂; diethyl ether / Ambient temperature

With dimethylaluminum chloride; sodium iodide; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00168a065

Reference yield:

: 127358-55-8
2-Benzenesulfonyl-2-(2-trimethylsilanylmethyl-buta-2,3-dienyl)-cyclopentanone

: 127358-59-2
6a-Benzenesulfonyl-2,3-dimethylene-hexahydro-pentalen-3a-ol

: 127358-60-5
6a-Benzenesulfonyl-4-chloromethyl-5-trimethylsilanylmethyl-2,3,6,6a-tetrahydro-1H-pentalen-3a-ol

Guidance literature:: With dimethylaluminum chloride; In diethyl ether; dichloromethane; Yield given. Yields of byproduct given; Ambient temperature;
DOI:10.1021/ja00168a065