2-{ethoxy-[3-(2-nitrophenyldisulfanyl)phenyl]methylene}tricyclo[3.3.1.1^3,7]decane

Base Information

• Chemical Name: 2-{ethoxy-[3-(2-nitrophenyldisulfanyl)phenyl]methylene}tricyclo[3.3.1.1^3,7]decane
• CAS No.: 433711-33-2
• Molecular Formula: C₂₅H₂₇NO₃S₂
• Molecular Weight: 453.626

Synonyms:2-{ethoxy-[3-(2-nitrophenyldisulfanyl)phenyl]methylene}tricyclo[3.3.1.1^3,7]decane

Chemical Property of 2-{ethoxy-[3-(2-nitrophenyldisulfanyl)phenyl]methylene}tricyclo[3.3.1.1^3,7]decane

Chemical Property:

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Technology Process of 2-{ethoxy-[3-(2-nitrophenyldisulfanyl)phenyl]methylene}tricyclo[3.3.1.1^3,7]decane

There total 6 articles about 2-{ethoxy-[3-(2-nitrophenyldisulfanyl)phenyl]methylene}tricyclo[3.3.1.1^3,7]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

2-Nitrobenzenesulfonyl chloride (1694-92-4) + 2-[1-(3-(tert-butylsulfanyl)phenyl)-1-ethoxymethylene]tricyclo[3.3.1.13,7]decane (287171-79-3) → 2-{ethoxy-[3-(2-nitrophenyldisulfanyl)phenyl]methylene}tricyclo[3.3.1.13,7]decane (433711-33-2)

Guidance literature:

In tetrahydrofuran; for 2h;

DOI:10.1016/S0040-4039(02)00617-2

Reference yield: 26.0%

2-nitrobenzenesulfenyl chloride (7669-54-7) + 2-[1-(3-(tert-butylsulfanyl)phenyl)-1-ethoxymethylene]tricyclo[3.3.1.13,7]decane (287171-79-3) → 2-{ethoxy-[3-(2-nitrophenyldisulfanyl)phenyl]methylene}tricyclo[3.3.1.13,7]decane (433711-33-2)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 2h;

DOI:10.1021/ja0171299

Reference yield:

2-Adamantanone (700-58-3) → 2-{ethoxy-[3-(2-nitrophenyldisulfanyl)phenyl]methylene}tricyclo[3.3.1.13,7]decane (433711-33-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 60 percent / TiCl₃; LiAlH₄; NEt₃ / tetrahydrofuran / Heating

2: 26 percent / tetrahydrofuran / 2 h / 20 °C

With lithium aluminium tetrahydride; titanium(III) chloride; triethylamine; In tetrahydrofuran; 1: McMurry coupling;

DOI:10.1021/ja0171299

upstream raw materials:

2-nitrobenzenesulfenyl chloride

2-[1-(3-(tert-butylsulfanyl)phenyl)-1-ethoxymethylene]tricyclo[3.3.1.1^3,7]decane

2-Nitrobenzenesulfonyl chloride

2-Adamantanone

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