N-glycylaniline hydrobromide

Base Information

• Chemical Name: N-glycylaniline hydrobromide
• CAS No.: 106880-84-6
• Molecular Formula: BrH*C₈H₁₀N₂O
• Molecular Weight: 231.092
• Mol file: 106880-84-6.mol

Synonyms:N-glycylaniline hydrobromide

Chemical Property of N-glycylaniline hydrobromide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of N-glycylaniline hydrobromide

There total 2 articles about N-glycylaniline hydrobromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aniline (62-53-3) → N-glycylaniline hydrobromide (106880-84-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / N-ethyl-N'-((dimethylamino)propyl)carbodiimide hydrochloride / CH₂Cl₂ / 168 h / Ambient temperature

2: 84 percent / 1.) H₂; 2.) HBr / 10 percent Pd-C / ethanol / Ambient temperature

With hydrogen bromide; hydrogen; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; palladium on activated charcoal; In ethanol; dichloromethane;

DOI:10.1021/ja00240a036

Reference yield:

α-azidoacetanilide (10258-71-6) → N-glycylaniline hydrobromide (106880-84-6)

Guidance literature:

With hydrogen bromide; acetic acid; acetone;

Reference yield: 42.0%

trans-dibromobis(ethylenediamine)cobalt(III) bromide (14587-89-4,14911-27-4,15005-14-8) + N-glycylaniline hydrobromide (106880-84-6) → (+/-)-ab-(2-aminoacetanilide-O,N(2))-cf,de-bis(ethylenediamine-N,N')cobalt(3+) trinitrate hydrate

Guidance literature:

With silver nitrate; In ethanol; byproducts: AgCl; centrifugation, pellets discarded, supernatant chromd. on G-10 Sephadex (0.5 M HCO2H),then on Sephadex SP-25(0.1-1.0 M gradient elution), major 3+ orange band was collected, evapn., recrystn. from dilute nitric acid, elem. anal.;

DOI:10.1021/ja00240a036

upstream raw materials:

α-azidoacetanilide

aniline