V(CN(CH₃)2C₆H₃)6

Base Information

Chemical Name:V(CN(CH₃)2C₆H₃)6
CAS No.:200487-82-7
Molecular Formula:C₅₄H₅₄N₆V
Molecular Weight:838.004
Hs Code.:

V(CN(CH<sub>3</sub>)2C<sub>6</sub>H<sub>3</sub>)6

Synonyms:V(CN(CH₃)2C₆H₃)6

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Chemical Property of V(CN(CH₃)2C₆H₃)6

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Technology Process of V(CN(CH₃)2C₆H₃)6

There total 2 articles about V(CN(CH₃)2C₆H₃)6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: bis(1-methylnaphthalene)vanadium⁽⁰⁾

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 200487-82-7
V(CN(CH₃)2C₆H₃)6

Guidance literature:: In tetrahydrofuran; n-heptane; isocyanide addn. at 0°C to vanadium(0) complex, react. 12 h; solvent concn., filtration, recrystn. (THF/heptane); elem. anal.;
DOI:10.1021/ja9729239

Reference yield: 75.0%

: Cs⁽¹⁺⁾*2(CH₂)12O₆*V(CN(CH₃)2C₆H₃)6^(1-)=Cs((CH₂)12O₆)2V(CN(CH₃)2C₆H₃)6

: 200487-82-7
V(CN(CH₃)2C₆H₃)6

Guidance literature:: With Et₃NHCl; In tetrahydrofuran; V-complex in THF at -60°C was transferred into flask with Et3NHClin THF at -60°C, stirred for 2 h at -60°C, warmed to room temp. under Ar; filtered, heptane was added, concd., filtered off, washed with pentane, dried under vac. for 2 h;
DOI:10.1021/ja000212w

Reference yield: 96.0%

: 200487-82-7
V(CN(CH₃)2C₆H₃)6

: K⁽¹⁺⁾*(CH₂)18O₆N₂*C₁₀H₈^(1-)=K((CH₂)18O₆N₂)C₁₀H₈

: 272456-46-9
K⁽¹⁺⁾*(CH₂)18O₆N₂*V(CN(CH₃)2C₆H₃)6^(1-)=K((CH₂)18O₆N₂)V(CN(CH₃)2C₆H₃)6

Guidance literature:: In tetrahydrofuran; cold soln. of V-complex in THF was added to cold soln. of ligand in THF,stirred for 15 h, warmed to room temp. under Ar; filtered, washed with THF, pentane, ether, dried in vacuo for 4 h;
DOI:10.1021/ja000212w