methyl (3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

Base Information

Chemical Name:methyl (3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside
CAS No.:365535-22-4
Molecular Formula:C₄₆H₅₂O₁₂
Molecular Weight:796.912
Hs Code.:

Synonyms:methyl (3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

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Chemical Property of methyl (3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

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Technology Process of methyl (3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

There total 1 articles about methyl (3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 2774-19-8,14419-69-3,15887-67-9,23392-28-1,57539-08-9,61277-63-2,74410-51-8,76419-48-2,80734-73-2,86363-44-2,89301-79-1,94061-92-4,94062-87-0,108739-92-0,129706-93-0,143005-12-3,65877-21-6
(2R,4aR,6S,7S,8R,8aR)-8-Benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

: 365534-69-6
2-(hydroxycarbonyl)benzyl 3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranoside

: 365535-22-4
methyl (3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

Guidance literature:: 2-(hydroxycarbonyl)benzyl 3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranoside; With 2,6-di-tert-butyl-4-methylpyridine; trifluoromethylsulfonic anhydride; 4 A molecular sieve; In dichloromethane; at -78 ℃; for 0.5h;

(2R,4aR,6S,7S,8R,8aR)-8-Benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol; In dichloromethane; at -78 - 0 ℃; for 2.5h; Further stages.;
DOI:10.1021/ja015842s

Reference yield: 99.0%

: 365535-22-4
methyl (3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

: 192936-03-1
methyl O-(3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

Guidance literature:: With sodium methylate; In methanol; for 50h; Heating;
DOI:10.1021/ja015842s

Reference yield:

: 365535-22-4
methyl (3-O-benzyl-4,6-O-benzylidene-2-O-pivaloyl-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

: methyl [(3-O-benzyl-4,6-O-benzylidene-2-O-pyvaloyl-α-D-mannopyranosyl)-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyl]-(1->2)-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: 99 percent / NaOMe / methanol / 50 h / Heating

2.1: 2,6-di-tert-butyl-4-methylpyridine; 4 Angstroem molecular sieves; (CF₃SO₂)2O / CH₂Cl₂ / 0.5 h / -78 °C

2.2: 83 percent / CH₂Cl₂ / 2.5 h / -78 - 0 °C

With 2,6-di-tert-butyl-4-methylpyridine; trifluoromethylsulfonic anhydride; 4 A molecular sieve; sodium methylate; In methanol; dichloromethane;
DOI:10.1021/ja015842s