[5-(4-Methoxy-benzyloxy)-4,4-dimethyl-hept-6-en-1-ynyl]-trimethyl-silane

Base Information

Chemical Name:[5-(4-Methoxy-benzyloxy)-4,4-dimethyl-hept-6-en-1-ynyl]-trimethyl-silane
CAS No.:135789-11-6
Molecular Formula:C₂₀H₃₀O₂Si
Molecular Weight:330.543
Hs Code.:

Synonyms:[5-(4-Methoxy-benzyloxy)-4,4-dimethyl-hept-6-en-1-ynyl]-trimethyl-silane

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Chemical Property of [5-(4-Methoxy-benzyloxy)-4,4-dimethyl-hept-6-en-1-ynyl]-trimethyl-silane

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Technology Process of [5-(4-Methoxy-benzyloxy)-4,4-dimethyl-hept-6-en-1-ynyl]-trimethyl-silane

There total 2 articles about [5-(4-Methoxy-benzyloxy)-4,4-dimethyl-hept-6-en-1-ynyl]-trimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 106211-55-6
2,2-dimethyl-5-(trimethylsilyl) pent-4-yn-1-ol

: 135789-11-6
[5-(4-Methoxy-benzyloxy)-4,4-dimethyl-hept-6-en-1-ynyl]-trimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: (COCl)2, DMSO

With oxalyl dichloride; dimethyl sulfoxide;
DOI:10.1021/ja00019a051

Reference yield:

: 106211-57-8
2,2-dimethyl-5-(trimethylsilyl) pent-4-ynal

: 135789-11-6
[5-(4-Methoxy-benzyloxy)-4,4-dimethyl-hept-6-en-1-ynyl]-trimethyl-silane

Guidance literature:: DOI:10.1021/ja00019a051

Reference yield:

: 135789-11-6
[5-(4-Methoxy-benzyloxy)-4,4-dimethyl-hept-6-en-1-ynyl]-trimethyl-silane

: 135760-92-8
(1R,3aR,5aS,6R,8aR)-6-(4-Methoxy-benzyloxy)-1,7,7-trimethyl-octahydro-cyclopenta[c]pentalen-4-one

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) n-BuLi, Cp₂ZrCl₂ / 1.) THF, -78 deg C to 20 deg C, overnight, 2.) -20 deg C, 3 h

2: 1.) n-BuLi, 2.) n-Bu₄NF / 1.) THF, -78 deg C, 15 min, 2.) THF, 0 deg C, 5 min

3: PPTS / benzene

4: 1.) BH₃*THF, 2.) 30percent H₂O₂, aq. NaOAc / 1.) THF, 20 deg C, 16 h, 2.) 50 deg C, 15 min

5: 76 percent / NaHCO₃ / methanol; H₂O / 3 h / Heating

With n-butyllithium; zirconocene dichloride; borane-THF; tetrabutyl ammonium fluoride; dihydrogen peroxide; sodium acetate; pyridinium p-toluenesulfonate; sodium hydrogencarbonate; In methanol; water; benzene;
DOI:10.1021/ja00019a051