C₂₆H₄₂O₆Si

Base Information

• Chemical Name: C₂₆H₄₂O₆Si
• CAS No.: 884004-86-8
• Molecular Formula: C₂₆H₄₂O₆Si
• Molecular Weight: 478.701
• Mol file: 884004-86-8.mol

Synonyms:C₂₆H₄₂O₆Si

Chemical Property of C₂₆H₄₂O₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₆H₄₂O₆Si

There total 20 articles about C₂₆H₄₂O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C26H40O6Si (884004-85-7) → C26H42O6Si (884004-86-8)

Guidance literature:

With diisobutylaluminium hydride; In hexane; dichloromethane; at -60 - 20 ℃; for 0.3h;

DOI:10.1002/chem.200500993

Reference yield:

C24H30O5 → C26H42O6Si (884004-86-8)

Guidance literature:

Multi-step reaction with 17 steps

1: 6.5 g / diethyl ether / 0.5 h / -65 - 20 °C

2: 85 percent / (i-Pr)2NEt

3: TiCl₄; TMEDA; Zn / PbCl₂ / CH₂Cl₂

4: PhCH=RuCH{[(Mes)NCH₂CH₂N(Mes)]}(PCy₃)Cl₂ / benzene / 20 °C

5: 92 percent / m-CPBA

6: 78 percent / NaH / tetrahydrofuran

7: PPTS; pyridine / toluene / 100 °C

8: 97 percent / DDQ; H₂O / CH₂Cl₂

9: DEAD; PPh₃ / toluene

10: NaOH / tetrahydrofuran; methanol

11: 97 percent / NEt₃ / dimethylformamide

12: 97 percent / NaBH₄ / ethanol / 2 h / -65 - 20 °C

13: 95 percent / TsOH*H₂O / various solvent(s) / 0.5 h / 0 °C

14: 98 percent / NEt₃; TMSOTf / CH₂Cl₂ / 1 h / -60 - 0 °C

15: 95 percent / PhCH=Ru{[(Mes)NCH₂CH₂N(Mes)]}(PCy₃)Cl₂ / benzene / 8 h / 20 °C

16: dimethyldioxirane / CH₂Cl₂; acetone / 0.5 h / -60 - 20 °C

17: 2.0 mg / i-Bu₂AlH / CH₂Cl₂; hexane / 0.3 h / -60 - 20 °C

With pyridine; sodium hydroxide; sodium tetrahydroborate; N,N,N,N,-tetramethylethylenediamine; trimethylsilyl trifluoromethanesulfonate; water; 3,3-dimethyldioxirane; pyridinium p-toluenesulfonate; titanium tetrachloride; sodium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; triethylamine; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; diethylazodicarboxylate; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; lead(II) chloride; In tetrahydrofuran; methanol; diethyl ether; ethanol; hexane; dichloromethane; N,N-dimethyl-formamide; acetone; toluene; benzene; 9: Mitsunobu inversion;

DOI:10.1002/chem.200500993

Reference yield:

C30H40O5 → C26H42O6Si (884004-86-8)

Guidance literature:

Multi-step reaction with 14 steps

1: PhCH=RuCH{[(Mes)NCH₂CH₂N(Mes)]}(PCy₃)Cl₂ / benzene / 20 °C

2: 92 percent / m-CPBA

3: 78 percent / NaH / tetrahydrofuran

4: PPTS; pyridine / toluene / 100 °C

5: 97 percent / DDQ; H₂O / CH₂Cl₂

6: DEAD; PPh₃ / toluene

7: NaOH / tetrahydrofuran; methanol

8: 97 percent / NEt₃ / dimethylformamide

9: 97 percent / NaBH₄ / ethanol / 2 h / -65 - 20 °C

10: 95 percent / TsOH*H₂O / various solvent(s) / 0.5 h / 0 °C

11: 98 percent / NEt₃; TMSOTf / CH₂Cl₂ / 1 h / -60 - 0 °C

12: 95 percent / PhCH=Ru{[(Mes)NCH₂CH₂N(Mes)]}(PCy₃)Cl₂ / benzene / 8 h / 20 °C

13: dimethyldioxirane / CH₂Cl₂; acetone / 0.5 h / -60 - 20 °C

14: 2.0 mg / i-Bu₂AlH / CH₂Cl₂; hexane / 0.3 h / -60 - 20 °C

With pyridine; sodium hydroxide; sodium tetrahydroborate; trimethylsilyl trifluoromethanesulfonate; water; 3,3-dimethyldioxirane; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; triethylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; diethylazodicarboxylate; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; N,N-dimethyl-formamide; acetone; toluene; benzene; 6: Mitsunobu inversion;

DOI:10.1002/chem.200500993

upstream raw materials:

C₂₆H₄₀O₆Si

C₂₈H₄₄O₅Si

[2-(3-benzyloxy-propyl)-4a,10a-dimethyl-3,4,4a,5,8a,9,9a,10a-octahydro-2H-1,8,10-trioxa-anthracen-4-yloxy]-trimethyl-silane

(2S,4R)-2-(3-Benzyloxy-propyl)-5-methyl-3,4-dihydro-2H-pyran-4-ol