α-dichloromethyl phenylsulfoxide

Base Information

• Chemical Name: α-dichloromethyl phenylsulfoxide
• CAS No.: 30058-54-9
• Molecular Formula: C₇H₆Cl₂OS
• Molecular Weight: 209.096
• Mol file: 30058-54-9.mol

Synonyms:α-dichloromethyl phenylsulfoxide

Chemical Property of α-dichloromethyl phenylsulfoxide

Chemical Property:

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α-dichloromethyl phenylsulfoxide

There total 5 articles about α-dichloromethyl phenylsulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

racemic methyl phenyl sulfoxide (1193-82-4) → α-dichloromethyl phenylsulfoxide (30058-54-9)

Guidance literature:

With N-chloro-succinimide; In tetrahydrofuran; at 20 ℃;

DOI:10.1016/j.tetlet.2007.05.049

Reference yield:

→ α-dichloromethyl phenylsulfoxide (30058-54-9)

Guidance literature:

With sodium hypochlorite;

DOI:10.1039/jr9560000508

Reference yield:

ethyl phenylsulfenylacetate (7605-25-6) → α-dichloromethyl phenylsulfoxide (30058-54-9)

Guidance literature:

With sodium hypochlorite; β‐cyclodextrin; In ethanol; water; Quantum yield; other oxidants;

DOI:10.1039/c39890000342

upstream raw materials:

ethyl phenylsulfenylacetate

tert-butyl (phenylthio)acetate

racemic methyl phenyl sulfoxide

Downstream raw materials:

2-(2-Benzenesulfinyl-2,2-dichloro-ethyl)-1-chloro-4-methoxy-benzene

C₁₅H₁₄Cl₂O₂S₂

C₁₉H₂₀Cl₂O₂S

C₁₉H₂₀Cl₂O₂S

Refernces

• 1、 Saleh, Basil A.,Smith, Keith,Elliott, Mark C.,Jones, D. Heulyn,Kariuki, Benson M.,El Hiti, Gamal A.. "Reactions of organoboranes with carbanions bearing three potential leaving groups: unusual processes, products and mechanisms". . p. 6914 - 6928. Retrieved 2016/10/14.