2(R),3-dihydroxypropyl 1',3',4',5'-tetra-O-benzyl-β-D-fructopyranoside 2,3-di-dodecanoate

Base Information

Chemical Name:2(R),3-dihydroxypropyl 1',3',4',5'-tetra-O-benzyl-β-D-fructopyranoside 2,3-di-dodecanoate
CAS No.:890085-33-3
Molecular Formula:C₆₁H₈₆O₁₀
Molecular Weight:979.348
Hs Code.:

Synonyms:2(R),3-dihydroxypropyl 1',3',4',5'-tetra-O-benzyl-β-D-fructopyranoside 2,3-di-dodecanoate

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Chemical Property of 2(R),3-dihydroxypropyl 1',3',4',5'-tetra-O-benzyl-β-D-fructopyranoside 2,3-di-dodecanoate

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Technology Process of 2(R),3-dihydroxypropyl 1',3',4',5'-tetra-O-benzyl-β-D-fructopyranoside 2,3-di-dodecanoate

There total 4 articles about 2(R),3-dihydroxypropyl 1',3',4',5'-tetra-O-benzyl-β-D-fructopyranoside 2,3-di-dodecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 890085-30-0
2(R),3-dihydroxypropyl 1',3',4',5'-tetra-O-benzyl-β-D-fructopyranoside

: 112-16-3
n-dodecanoyl chloride

: 890085-33-3
2(R),3-dihydroxypropyl 1',3',4',5'-tetra-O-benzyl-β-D-fructopyranoside 2,3-di-dodecanoate

Guidance literature:: In pyridine; dichloromethane; at 20 ℃; for 2h;
DOI:10.1016/j.carres.2006.02.005

Reference yield:

: 890085-31-1
allyl 1,3,4,5-tetra-O-benzyl-β-D-fructopyranoside

: 890085-33-3
2(R),3-dihydroxypropyl 1',3',4',5'-tetra-O-benzyl-β-D-fructopyranoside 2,3-di-dodecanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 50 percent / K₂CO₃; K₃Fe(CN)6; chiral ligand / potassium(IV)osmate-dihydrate / 2-methyl-propan-2-ol; H₂O / 12 h

2: 91 percent / pyridine; CH₂Cl₂ / 2 h / 20 °C

With potassium carbonate; potassium hexacyanoferrate(III); potassium(VI)osmate; In pyridine; dichloromethane; water; tert-butyl alcohol; 1: Sharpless-type asymmetric dihydroxylation;
DOI:10.1016/j.carres.2006.02.005

Reference yield:

: 100-44-7
benzyl chloride

: 890085-33-3
2(R),3-dihydroxypropyl 1',3',4',5'-tetra-O-benzyl-β-D-fructopyranoside 2,3-di-dodecanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 79.5 percent / KOH; Me₂SO / 12 h / 20 °C

2: 50 percent / K₂CO₃; K₃Fe(CN)6; chiral ligand / potassium(IV)osmate-dihydrate / 2-methyl-propan-2-ol; H₂O / 12 h

3: 91 percent / pyridine; CH₂Cl₂ / 2 h / 20 °C

With potassium hydroxide; potassium carbonate; dimethyl sulfoxide; potassium hexacyanoferrate(III); potassium(VI)osmate; In pyridine; dichloromethane; water; tert-butyl alcohol; 2: Sharpless-type asymmetric dihydroxylation;
DOI:10.1016/j.carres.2006.02.005