Rh₂(C₉NH₆COO)2(CO)2(P(C₆H₅)2CH₂P(C₆H₅)2)

Base Information

• Chemical Name: Rh₂(C₉NH₆COO)2(CO)2(P(C₆H₅)2CH₂P(C₆H₅)2)
• CAS No.: 157312-94-2
• Molecular Formula: C₄₇H₃₄N₂O₆P₂Rh₂
• Molecular Weight: 990.555
• Mol file: 157312-94-2.mol

Synonyms:Rh₂(C₉NH₆COO)2(CO)2(P(C₆H₅)2CH₂P(C₆H₅)2)

Chemical Property of Rh₂(C₉NH₆COO)2(CO)2(P(C₆H₅)2CH₂P(C₆H₅)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rh₂(C₉NH₆COO)2(CO)2(P(C₆H₅)2CH₂P(C₆H₅)2)

There total 1 articles about Rh₂(C₉NH₆COO)2(CO)2(P(C₆H₅)2CH₂P(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

(2-quinaldinate)(carbonyl)2rhodium(I) (20094-24-0) + bis-diphenylphosphinomethane (2071-20-7) → Rh2(C9NH6COO)2(CO)2(P(C6H5)2CH2P(C6H5)2) (157312-94-2)

Guidance literature:

In acetone; under N2; the phosphine was added to a suspn. of the Rh complex in acetone in the darkness, stirred for 17 h; filtered, washed with acetone, recrystd. from CH2Cl2/Et2O-hexane, dried in vac.; elem. anal.;

DOI:10.1016/S0277-5387(00)83451-8

Reference yield: 80.0%

Rh2(C9NH6COO)2(CO)2(P(C6H5)2CH2P(C6H5)2) (157312-94-2) → 2Rh(3+)*4I(1-)*2C9NH6COO(1-)*2CO*P(C6H5)2CH2P(C6H5)2=Rh2I4(C9NH6COO)2(CO)2(P(C6H5)2CH2P(C6H5)2)

Guidance literature:

With I₂; In dichloromethane; under N2; addn. of I2 in CH2Cl2 in the darkness to the Rh complex in CH2Cl2, stirred for 1 h; filtered, washed with CH2Cl2, dried in vac.; elem. anal.;

DOI:10.1016/S0277-5387(00)83451-8

Reference yield: 65.0%

Rh2(C9NH6COO)2(CO)2(P(C6H5)2CH2P(C6H5)2) (157312-94-2) + bis-diphenylphosphinomethane (2071-20-7) → Rh(C9NH6COO)(P(C6H5)2CH2P(C6H5)2) (157252-09-0)

Guidance literature:

In acetone; under N2; to a suspn. of the Rh complex in acetone was added the phosphine, stirred for 5 h; filtered, washed with acetone, dried in vac.;

DOI:10.1016/S0277-5387(00)83451-8

upstream raw materials:

(2-quinaldinate)(carbonyl)2rhodium(I)

bis-diphenylphosphinomethane

Downstream raw materials:

Rh(C₉NH₆COO)(P(C₆H₅)2CH₂P(C₆H₅)2)