C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

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Chemical Name:C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆
CAS No.:74561-64-1
Molecular Formula:CHCl₃*C₃₀H₂₆NOPRe*F₆P
Molecular Weight:898.065
Hs Code.:

C<sub>5</sub>H<sub>5</sub>Re(NO)CHC<sub>6</sub>H<sub>5</sub>P(C<sub>6</sub>H<sub>5</sub>)3<sup>(1+)</sup>*PF<sub>6</sub><sup>(1-)</sup>=Re(C<sub>5</sub>H<sub>5</sub>)NOP(C<sub>6</sub>H<sub>5</sub>)3CHC<sub>6</sub>H<sub>5</sub>PF<sub>6</sub>

Synonyms:C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

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Chemical Property of C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

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Technology Process of C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

There total 4 articles about C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 82399-52-8
C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3

: 437-17-2
tritylium hexafluorophosphate

: 74561-64-1
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)*CHCl₃=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆*CHCl₃

Guidance literature:: In dichloromethane-d2; byproducts: Ph3CH; soln. of Re-complex in CD2Cl2 was cooled to -78°C, ligand in CD2Cl2 was added, tube was quickly transferred to -73°C NMR probe, warmed to room temp. for several h, applied silica gel TLC plate, eluted with ethyl acetate/hexanes; concd., residue recrystd. from hot EtOH, extd. with CH2Cl2, concd., residue recrystd. from CHCl3/petroleum ether;
DOI:10.1021/ja00382a021

Reference yield:

: (η-C5H5)Re(NO)(PPh3)(CH(OCH3)C6H5)

: 437-17-2
tritylium hexafluorophosphate

: 74561-64-1
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

Guidance literature:: In dichloromethane-d2; byproducts: Ph3COCH3; soln. of Re-complex in CD2Cl2 was cooled to -78°C, ligand in CD2Cl2, tube was quickly transferred to -65°C NMR probe; monitored by NMR;
DOI:10.1021/ja00382a021

Reference yield:

: (η(5)-cyclopentadienyl)Re(NO)(P(C6H5)3)(benzyl)

: 74540-78-6
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

: 437-17-2
tritylium hexafluorophosphate

: 74561-64-1
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

Guidance literature:: In dichloromethane-d2; soln. of Re-complex in CD2Cl2 was cooled to 4-29.5°C, soln. of ligand in CD2Cl2 was added; monitored by NMR; Kinetics;
DOI:10.1021/ja00382a021