trans-carbonyl(sulfonylnitride)bis(triphenylphosphine)rhodium(I)

Base Information

• Chemical Name: trans-carbonyl(sulfonylnitride)bis(triphenylphosphine)rhodium(I)
• CAS No.: 136214-86-3
• Molecular Formula: C₃₇H₃₀NO₃P₂RhS
• Molecular Weight: 733.569
• Mol file: 136214-86-3.mol

Synonyms:trans-carbonyl(sulfonylnitride)bis(triphenylphosphine)rhodium(I)

Chemical Property of trans-carbonyl(sulfonylnitride)bis(triphenylphosphine)rhodium(I)

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of trans-carbonyl(sulfonylnitride)bis(triphenylphosphine)rhodium(I)

There total 1 articles about trans-carbonyl(sulfonylnitride)bis(triphenylphosphine)rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

fluorocarbonylbis(triphenylphosphine)rhodium(I) (58167-05-8,22481-17-0) + cesium sulfonylnitride → trans-carbonyl(sulfonylnitride)bis(triphenylphosphine)rhodium(I) (136214-86-3)

Guidance literature:

In acetonitrile; byproducts: CsF; (N2); refluxing (4 h); filtration, concn. (reduced pressure), pptn. on cooling, filtration, washing (cold CH3CN), drying (N2); elem. anal.;

DOI:10.1016/S0020-1693(00)90151-8

Reference yield: 67.0%

trans-carbonyl(sulfonylnitride)bis(triphenylphosphine)rhodium(I) (136214-86-3) → trans-carbonyl(thionitro)bis(triphenylphosphine)rhodium(I)

Guidance literature:

With PPh₃; In acetonitrile; byproducts: OPPh3; (N2); refluxing (2 h); concn. (reduced pressure), pptn. on cooling, filtration, washing (cold CH3CN), drying (N2); elem. anal.;

DOI:10.1016/S0020-1693(00)90151-8

upstream raw materials:

fluorocarbonylbis(triphenylphosphine)rhodium(I)