IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)⁽¹⁺⁾*B(C₆H₅)4^(1-)={IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)}{B(C₆H₅)4}

Base Information

• Chemical Name: IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)⁽¹⁺⁾*B(C₆H₅)4^(1-)={IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)}{B(C₆H₅)4}
• CAS No.: 155806-17-0
• Molecular Formula: C₂₄H₂₀B*C₄₉H₄₇IrP₃S
• Molecular Weight: 1272.35

Synonyms:IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)⁽¹⁺⁾*B(C₆H₅)4^(1-)={IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)}{B(C₆H₅)4}

Chemical Property of IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)⁽¹⁺⁾*B(C₆H₅)4^(1-)={IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)}{B(C₆H₅)4}

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Technology Process of IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)⁽¹⁺⁾*B(C₆H₅)4^(1-)={IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)}{B(C₆H₅)4}

There total 3 articles about IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)⁽¹⁺⁾*B(C₆H₅)4^(1-)={IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)}{B(C₆H₅)4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[(1,1,1-tris(diphenylphosphinomethyl)ethane)Ir(H)2(THF)]BPh4 (142928-68-5) + Benzo[b]thiophene (95-15-8,11095-43-5) → IrH2(CH3C(CH2P(C6H5)2)3)(C8H6S)(1+)*B(C6H5)4(1-)={IrH2(CH3C(CH2P(C6H5)2)3)(C8H6S)}{B(C6H5)4} (155806-17-0)

Guidance literature:

In dichloromethane; under N2; to a soln. of the benzothiophene in CH2Cl2 was added the Ir complex; addn. of pentane, partial evapn.; elem. anal.;

DOI:10.1021/ja00089a027

Reference yield:

Ir(CH3C(CH2P(C6H5)2)3)(C8H6S)(1+)*B(C6H5)4(1-)={Ir(CH3C(CH2P(C6H5)2)3)(C8H6S)}{B(C6H5)4} (155806-13-6) → IrH2(CH3C(CH2P(C6H5)2)3)(C8H6S)(1+)*B(C6H5)4(1-)={IrH2(CH3C(CH2P(C6H5)2)3)(C8H6S)}{B(C6H5)4} (155806-17-0)

Guidance literature:

With H₂; In tetrahydrofuran; under N2; H2 was bubbled through a soln. of the Ir complex in THF at room temp. for 3 h; concd. to dryness in vac., identified by IR and NMR;

DOI:10.1021/ja00089a027

Reference yield:

Ir(CH3C(CH2P(C6H5)2)3)(C8H6S)(1+)*B(C6H5)4(1-)={Ir(CH3C(CH2P(C6H5)2)3)(C8H6S)}{B(C6H5)4} (155806-13-6) → (1,1,1-tris(diphenylphosphinomethyl)ethane)Ir(H)3 (104453-08-9) + IrH2(CH3C(CH2P(C6H5)2)3)(C8H6S)(1+)*B(C6H5)4(1-)={IrH2(CH3C(CH2P(C6H5)2)3)(C8H6S)}{B(C6H5)4} (155806-17-0)

Guidance literature:

With H₂; In toluene; byproducts: benzo{b}thiophene, triphenylboron, benzene; under N2; a soln. of the Ir complex in toluene was pressurized with H2 to 5 atm at room temp. for 3 h; concd. to dryness in vac., identified by IR and NMR;

DOI:10.1021/ja00089a027

upstream raw materials:

Ir(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)⁽¹⁺⁾*B(C₆H₅)4^(1-)={Ir(CH₃C(CH₂P(C₆H₅)2)3)(C₈H₆S)}{B(C₆H₅)4}

[(1,1,1-tris(diphenylphosphinomethyl)ethane)Ir(H)2(THF)]BPh₄

Benzo[b]thiophene

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