phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

Base Information

Chemical Name:phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside
CAS No.:1363902-10-6
Molecular Formula:C₉₉H₁₁₄O₂₂SSi
Molecular Weight:1716.13
Hs Code.:

phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

Synonyms:phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

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Chemical Property of phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

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Technology Process of phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

There total 1 articles about phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1363902-83-3
phenyl [2-O-acetyl-6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

: 1363902-10-6
phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

Guidance literature:: phenyl [2-O-acetyl-6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside; With sodium methylate; In methanol; dichloromethane; at 20 ℃; Inert atmosphere;

In methanol; dichloromethane; pH=7; Inert atmosphere;
DOI:10.1002/chem.201102545

Reference yield: 44.0%

: 1227636-93-2
C₃₄H₃₈Cl₃NO₁₀

: 1363902-10-6
phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

: phenyl [2-O-acetyl-3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

Guidance literature:: C₃₄H₃₈Cl₃NO₁₀; phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere; Molecular sieve;

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 0 ℃; for 0.166667h; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1002/chem.201102545

Reference yield:

: 1363903-03-0
2,3,4,6-tetra-O-(p-methoxybenzyl)-α-D-mannopyranosyl trichloroacetimidate

: 1363902-10-6
phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

: phenyl [2,3,4,6-tetra-O-(p-methoxybenzyl)-β-D-mannopyranosyl]-(1->2)-[6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

: phenyl [2,3,4,6-tetra-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside

Guidance literature:: 2,3,4,6-tetra-O-(p-methoxybenzyl)-α-D-mannopyranosyl trichloroacetimidate; phenyl [6-O-(tert-butyldiphenylsilyl)-3,4-di-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->2)-[3,4,6-tri-O-(p-methoxybenzyl)-α-D-mannopyranosyl]-(1->6)-2-O-allyl-3,4-di-O-(p-methoxybenzyl)-1-thio-α-D-mannopyranoside; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere; Molecular sieve;

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 0 ℃; for 0.166667h; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1002/chem.201102545